Palladium catalyst imbedded in polymers of intrinsic microporosity for the Suzuki-Miyaura coupling reaction

被引：7
作者：
Xu, Junwen [1 ,2 ]
Ou, Junjie [1 ]
Chen, Lianfang [1 ,2 ]
Zhang, Haiyang [1 ]
Ma, Shujuan [1 ]
Ye, Mingliang [1 ]
机构：
[1] Chinese Acad Sci, Dalian Inst Chem Phys, Key Lab Separat Sci Analyt Chem, Dalian 116023, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
来源：
RSC ADVANCES | 2018年 / 8卷 / 61期
关键词：
EFFICIENT CATALYST; ORGANIC FRAMEWORK; HYDROGEN STORAGE; PERFORMANCE; MEMBRANES; CARBON; OXIDATION; PIMS;
D O I：
10.1039/c8ra06214e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Polymers of intrinsic microporosity (PIMs) are porous polymers with rigid ladder-type chain structures. Synthesizing these polymers usually involves the step polymerization of two types of monomer, namely, active fluorine-substituted aromatic ring monomers and phenolic monomers. Herein, we report a new PIMs preparation method using self-synthesized fluorinated monomers and common monomer 5,5,6,6-tetrahydroxy-3,3,3,3-tetramethyl spirobisindane. The fluorinated monomers were synthesized through the imidization of tetrafluorophthalic anhydride and aromatic diamines. The resulting PIMs served as a support for palladium, with the formed catalyst showing potential for application in the Suzuki-Miyaura coupling reaction.
引用
收藏
页码：35205 / 35210
页数：6
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