Pd-Catalyzed Oxidative Cross-Coupling of Perfluoroarenes with Aromatic Heterocycles

被引：271
|
作者：
He, Chun-Yang [1 ]
Fan, Shilu [1 ]
Zhang, Xingang [1 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 37期
关键词：
C-H FUNCTIONALIZATION; THIN-FILM TRANSISTORS; DIRECT ARYLATION; ORGANIC SEMICONDUCTORS; ARENES; OLIGOFLUOROBENZENES; OLIGOTHIOPHENES; DERIVATIVES; ACTIVATION; MECHANISM;
D O I：
10.1021/ja106046p
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A straightforward and practical method for direct Pd(OAc)(2)-catalyzed oxidative cross-coupling of electron-deficient perfluoroarenes with aromatic heterocycles has been developed. Because of its low catalyst loading (2.5 mol %), high reaction efficiency, good chemo- and regioselectivity, and excellent functional-group compatibility, this protocol provides a useful and operationally simple access to perfluoroarene thiophene structures of interest in functional materials for electronic devices.
引用
收藏
页码：12850 / 12852
页数：3
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