Tackiness of an electrically conducting polyurethane-nanotube nanocomposite

被引:28
作者
Fernandez, Mercedes
Landa, Maite
Munoz, M. Eugenia
Santamaria, Anton [1 ]
机构
[1] Univ Basque Country, Fac Chem, Polymer Sci & Technol Dept, UPV EHU, San Sebastian 20080, Spain
关键词
Hot melt; Electrical properties; Composites; Polyurethane; GURP-PALMEN-PLOT; CARBON NANOTUBES; MELT; TACK; COMPOSITES; ADHESIVE; POLYCARBONATE; COPOLYMERS; VISCOELASTICITY; POLYETHYLENE;
D O I
10.1016/j.ijadhadh.2010.05.011
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Electrically conducting adhesive nanocomposites are obtained dispersing multiwall carbon nanotubes (MWCNT) in a thermoplastic polyurethane (TPU) by a melt mixing method. The liaison between the viscoelastic properties of the nanocomposites and their tackiness is investigated. Probe-tack results obtained at a low strain rate obey a polymer/nanotube interaction mechanism that favours tackiness, since maximum stress, strain at failure and adhesion energy increase with MWCNT concentration. However, in experiments at a high strain rate, the polymer entanglement network plays the principal role and MWCNTs only act diminishing the deformabilty of the network and reducing strain at failure and adhesion energy. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:609 / 614
页数:6
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