Macroreticular p-(ω-sulfonic-perfluoroalkylated) polystyrene ion-exchange resins:: a new type of selective solid acid catalyst

被引：13

作者：

Lin, ZH ^{[1
]}

Zhao, CX ^{[1
]}

机构：

[1] Shanghai Jiao Tong Univ, Dept Chem, Shanghai 200240, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 28期

关键词：

D O I：

10.1039/b504767f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Macroreticular p-(omega-sulfonic-perfluoroalkylated) polystyrene (FPS) cation-exchange resins 3 have been synthesized by sequential p-perfluoroalkylation of macroreticular polystyrene (PS) 1 with omega-fluorosulfonylperfluorodiacyl peroxide 2, hydrolysis and acidification; the fluorinated mesoporous resins exhibited higher activity and selectivity than commercial Amberlyst 36 and Nafion NR50 in the cyclization of pseudoionone.

引用

页码：3556 / 3558

页数：3

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