Single-Walled Metal-Organic Nanotube Built from a Simple Synthon

被引：37

作者：

Adarsh, Nayarassery N. ^{[1
]}

Dirtu, Marinela M. ^{[1
]}

Naik, Anil D. ^{[1
]}

Leonard, Alexandre F. ^{[2
]}

Campagnol, Nicolo ^{[3
]}

Robeyns, Koen ^{[1
]}

Snauwaert, Johan ^{[4
]}

Fransaer, Jan ^{[3
]}

Su, Bao Lian ^{[5
]}

Garcia, Yann ^{[1
]}

机构：

[1] Catholic Univ Louvain, Inst Condensed Matter & Nanosci Mol Solids React, B-1348 Louvain Le Neuve, Belgium

[2] Univ Liege, Lab Genie Chim Genie Catalyt, B-4000 Liege, Belgium

[3] Katholieke Univ Leuven, Dept Mat Engn, B-3001 Heverlee, Belgium

[4] Katholieke Univ Leuven, Lab Solid State Phys & Magnetism, B-3001 Heverlee, Belgium

[5] Univ Namur, Dept Chim, Lab Chim Mat Inorgan, B-5000 Namur, Belgium

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2015年 / 21卷 / 11期

关键词：

crystal engineering; electrodeposition; mercury intrusion; metal-organic frameworks; supramolecular chemistry; ELECTROCHEMICAL SYNTHESIS; COORDINATION POLYMERS; STRUCTURE VALIDATION; FRAMEWORKS; ADSORPTION; LIGANDS; MIL-53; FUNCTIONALIZATION; TRANSAMINATION; ARCHITECTURES;

D O I：

10.1002/chem.201405859

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A conformationally flexible triazole-carboxylic acid ligand derived from an l-amino acid, namely, 4H-1,2,4-triazol-4-yl-acetic acid (alpha HGlytrz), has been exploited to synthesize a structurally diverse and functionally intriguing metal-organic framework with CuSiF6. The crystal structure reveals a novel single-walled metal-organic nanotube (SWMONT), namely, {[Cu-3(m(3)-OH)(H2O)(3)(Glytrz)(3)]center dot SiF6 center dot 8H(2)O center dot X}(infinity) (1), (where X=disordered lattice water molecules) having a pore size as large as zeolites. Compound 1 was synthesized as crystals, as powder, or as layers by precipitation/electrodeposition. Mercury intrusion porosimetry demonstrates the ability of this material to store metallic mercury, after a pressure treatment, contrary to previous literature examples.

引用

页码：4300 / 4307

页数：8

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