Synthesis and aggregation study of optically active tetra-β-[(S)-2-octanyloxy]-substituted copper and nickel phthalocyanines

被引：2
作者：
Cong, Fang-Di [1 ,2 ]
Gao, Gui [3 ]
Li, Jian-Xin [2 ]
Huang, Guo-Qing [2 ]
Wei, Zhen [1 ]
Yu, Feng-Yang [1 ]
Du, Xi-Guang [1 ,2 ]
Xing, Ke-Zhi [1 ]
机构：
[1] Tianjin Agr Univ, Tianjin Key Lab Aquaecol & Aquaculture, Dept Basic Sci, Tianjin 300384, Peoples R China
[2] NE Normal Univ, Fac Chem, Changchun 130024, Peoples R China
[3] Jilin Univ, Key Lab Mol Enzymol & Engn, Minist Educ, Changchun 130021, Peoples R China
来源：
JOURNAL OF CHEMICAL SCIENCES | 2010年 / 122卷 / 06期
基金：
美国国家科学基金会;
关键词：
Synthesis; spectra; aggregation; chirality; ZINC; COMPLEXES;
D O I：
10.1007/s12039-010-0069-9
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The optically active tetra-beta-[(S)-2-octanyloxy]-substituted copper and nickel phthalocyanines were synthesized via a two-step route with 4-nitro-phthalonitrile and (S)-2-octanol as the starting materials. Both compounds are fully characterized by MS, H-1 NMR, UV-Vis, IR, CD and elemental analysis, and soluble in common organic solvents except methanol. The results showed that they were dispersed into single molecules in chloroform and dichloromethane, but prone to congregate into H-type aggregates in ethanol and diethyl ether. They assembled to H-type aggregates with left-handed helix when deposited as thin films.
引用
收藏
页码：813 / 818
页数：6
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