Investigation of the hydrogen interaction with Ti0.9Zr0.1Mn1.3V0.7 by means of the calorimetric method

被引：7

作者：

Anikina, E. Yu. ^{[1
]}

Verbetsky, V. N. ^{[1
]}

机构：

[1] Lomonosou Moscow State Univ, Chem Dept Moscow, Moscow 119991, Russia

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2016年 / 41卷 / 27期

关键词：

Intermetallic compound; Hydride; Ti0.9Zr0.1Mn1.3V0.7-H-2; system; Calorimetry;

D O I：

10.1016/j.ijhydene.2015.12.126

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In the present work we studied the hydrogen interaction with the stoichiometric Ti0.9Zr0.1Mn1.3V0.7 Laves phase compound C14 at pressure up to 50 atm and the temperature range from 52 to 130 degrees C by means of calorimetric method and plotting of pressure composition isotherms. The processes of hydrogen absorption and desorption were carried out. The findings enabled us to draw the following conclusions: 1) the experimental temperature influences the thermodynamic parameters of studied processes and 2) depending on reaction conditions the formation of one or two hydride phases takes place. (C) 2015 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：11520 / 11525

页数：6

共 19 条

[1]

Anikina E.Yu., 2006, NATO SCI SERIES A, P427

[2] Calorimetric investigation of the hydrogen interaction with Ti0.9Zr0.1Mn1.2V0.1 [J].

Anikina, Elena Yu ;

Verbetsky, Victor N. .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (01) :1344-1348

[3]

Anikina EY, 2004, NATO SCI SER II MATH, V172, P539

[4] Calorimetric investigation of the hydrogen interaction with Ti0.9Zr0.1Mn1.1V0.1 [J].

Anikina, EY ;

Verbetsky, VN .

JOURNAL OF ALLOYS AND COMPOUNDS, 2002, 330 :45-47

[5] SIGNIFICANCE OF THERMAL EFFECTS ASSOCIATED WITH SOLID-GAS REACTIONS IN TIAN-CALVET CALORIMETER [J].

BOUREAU, G ;

KLEPPA, OJ .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1977, 9 (06) :543-548

[6] NOMENCLATURE FOR THE PRESENTATION OF RESULTS OF CHEMICAL-ANALYSIS [J].

CURRIE, LA ;

SVEHLA, G .

PURE AND APPLIED CHEMISTRY, 1994, 66 (03) :595-608

[7] THE CHARACTERIZATION OF MULTICOMPONENT METAL-HYDRIDES USING REACTION CALORIMETRY [J].

FLANAGAN, TB ;

LUO, W ;

CLEWLEY, JD .

ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 1993, 179 :35-44

[8] THE THERMODYNAMICS OF THE SYSTEM ZR(FE0.75CR0.25)2 + H-2 USING HEAT-CONDUCTION CALORIMETRY [J].

GRANT, DM ;

MURRAY, JJ ;

POST, ML .

JOURNAL OF SOLID STATE CHEMISTRY, 1990, 87 (02) :415-422

[9] Thermodynamics of hydrogenation for Ti1-xZrxMnCr Laves phase alloys [J].

Guo, Mulnei ;

Wu, Erdong .

JOURNAL OF ALLOYS AND COMPOUNDS, 2008, 455 (1-2) :191-196

[10] THERMODYNAMIC PROPERTIES OF HYDROGEN AT PRESSURES UP TO 1 MBAR AND TEMPERATURES BETWEEN 100-K AND 1000-K [J].

HEMMES, H ;

DRIESSEN, A ;

GRIESSEN, R .

JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1986, 19 (19) :3571-3585

← 1 2 →