Molecular orbital confinement effect of mesoporous silica of MCM-41 on conjugated polymer

被引：21

作者：

Wang, BH ^{[1
]}

Xi, HA ^{[1
]}

Yin, J ^{[1
]}

Qian, XF ^{[1
]}

Zhu, ZK ^{[1
]}

机构：

[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Technol, Shanghai 200240, Peoples R China

来源：

SYNTHETIC METALS | 2003年 / 139卷 / 01期

关键词：

conjugated polymer; mesoporous silica; molecular orbital confinement effect; photoluminescence;

D O I：

10.1016/S0379-6779(03)00122-X

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A set of conjugated polymers with different molecular diameters was incorporated into channels of mesoporous silica of MCM-41. Study on UV-Vis and photoluminescent (PL) spectra of these composites revealed regular variation of band gap of frontier orbital along with the variation of diameter of the polymers by comparison with UV-Vis and PL spectra of the polymers in CHCl3 solution. The results showed evidence in support of the molecular orbital confinement effect in the composite of the conjugated polymer/mesoporous silica. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：187 / 190

页数：4

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