Aerobic Oxidative Coupling of Amines by Carbon Nitride Photocatalysis with Visible Light

被引：672

作者：

Su, Fangzheng ^{[1
]}

Mathew, Smitha C. ^{[2
]}

Moehlmann, Lennart ^{[2
]}

Antonietti, Markus ^{[1
]}

Wang, Xinchen ^{[1
,3
]}

Blechert, Siegfried ^{[2
]}

机构：

[1] Max Planck Inst Colloids & Interfaces, Dept Colloid Chem, D-14476 Potsdam, Germany

[2] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany

[3] Fuzhou Univ, Res Inst Photocatalysis, State Key Lab Breeding Base Photocatalysis, Fuzhou 350002, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 03期

关键词：

aerobic oxidative coupling; amines; carbon nitride; photochemistry; visible light; 2-SUBSTITUTED BENZOXAZOLES; C=N BOND; CATALYSIS; BENZIMIDAZOLES; BENZOTHIAZOLES; NANOPARTICLES; CLEAVAGE; BASES;

D O I：

10.1002/anie.201004365

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Coupling on sunshine: A simple and efficient synthesis of benzoxazoles, benzimidazoles, and benzothiazoles is realized through a one-pot preparation driven by a photocatalytic cascade reaction. Carbon nitride and visible light are employed to achieve this metal-free aerobic oxidation of amines to imines (see scheme; mpg-C3N4=mesoporous graphite carbon nitride). Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：657 / 660

页数：4

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