Controlled Atmosphere Brazing of 3003 Aluminum Alloy Using Low-Melting-Point Filler Metal Fabricated by Melt-Spinning Technology

被引:7
作者
Gao, Zeng [1 ]
Qin, Zhen [1 ]
Lu, Qingsong [2 ,3 ]
机构
[1] Henan Polytech Univ, Sch Mat Sci & Engn, Jiaozuo 454003, Henan, Peoples R China
[2] Zhejiang Yinlun Machinery Co Ltd, Taizhou 317200, Peoples R China
[3] Key Lab Smart Thermal Management Sci & Technol Ve, Taizhou 317200, Peoples R China
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
aluminum alloy; low melting point; filler metal; melt spinning; controlled atmosphere brazing; SI; CU; MICROSTRUCTURE; COMPOSITE; MECHANISM; MN; CE;
D O I
10.3390/ma15176080
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
3003 aluminum alloy was widely used for the manufacturing of heat exchangers in the automotive industry by employing controlled atmosphere brazing (CAB) with NOCOLOK flux brazing technology. However, commercially available filler metals for NOCOLOK flux brazing technology are usually required to be carried out at a relatively high temperature, causing the assembled heat exchanger to be partially molten or easily deformed. A new low-melting-point brazing filler metal Al-5.0Si-20.5Cu-2.0Ni was prepared by using melt-spinning technology and then applied to CAB of 3003 aluminum alloy in this research. The solidus and liquidus of brazing filler metal was 513.21 degrees C and 532.48 degrees C. All elements were evenly distributed and free from elemental segregation. The microstructure of brazing filler metal was uniform, and the grain size was less than 500 nm. As the brazing temperature reached 575 degrees C, the void in the joint disappeared completely. The morphology of CuAl2 was sensitive to the brazing temperature and dwell time. The appearance of net-like CuAl2 brazed at 575 degrees C for 20 min was more beneficial to improve joint mechanical properties. The leakage rate of the joint was qualified to be 10(-10) Pa center dot m(3)/s when the brazing temperature was 570 degrees C or higher. The maximum shear strength of 76.1 MPa can be obtained when the joint was brazed at 575 degrees C for 20 min. More dwell time induced growth of the interfacial layer and reduced joint shear strength. The open circuit potential and corrosion current density test indicated that the brazing filler metal Al-5.0Si-20.5Cu-2.0Ni had better corrosion resistance than that of 3003 aluminum alloy.
引用
收藏
页数:14
相关论文
共 29 条
  • [1] Internal Corrosion of Warm Formed Aluminum Alloy Automotive Heat Exchangers
    Benoit, M. J.
    Ogunsanya, I. G.
    Winkler, S.
    Worswick, M. J.
    Wells, M. A.
    Hansson, C. M.
    [J]. JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE, 2021, 30 (04) : 2876 - 2889
  • [2] Leak detection, calibrations and reference flows: Practical example
    Calcatelli, A.
    Bergoglio, M.
    Mari, D.
    [J]. VACUUM, 2007, 81 (11-12) : 1538 - 1544
  • [3] Cheng D.F., 2017, THESIS HENAN POLYTEC
  • [4] Cocian G, 2015, STUD U BABES-BOL CHE, V60, P187
  • [5] Development of low-melting-point filler materials for laser beam brazing of aluminum alloys
    Cui, C.
    Schulz, A.
    Achelis, L.
    Uhlenwinkel, V.
    Leopold, H.
    Piwek, V.
    Tang, Z.
    Seefeld, T.
    [J]. MATERIALWISSENSCHAFT UND WERKSTOFFTECHNIK, 2014, 45 (08) : 717 - 726
  • [6] Study on Novel Powder Metallurgy Al-Si Brazing Filler Metal with Flux
    Fei, Wenpan
    Wang, Bo
    Lou, Yinbin
    Long, Weimin
    Deng, Jianfeng
    Zhang, Lei
    Yin, Pengzhi
    Wang, Shuiqing
    [J]. CRYSTALS, 2022, 12 (04)
  • [7] Feng T, 2005, J UNIV SCI TECHNOL B, V12, P531
  • [8] Formation of Random Solid Solution in Multicomponent Alloys: from Hume-Rothery Rules to Entropic Stabilization
    He, Q. F.
    Ye, Y. F.
    Yang, Y.
    [J]. JOURNAL OF PHASE EQUILIBRIA AND DIFFUSION, 2017, 38 (04) : 416 - 425
  • [9] Investigation of pseudo-ternary system AlF3-KF-KCl
    Hu, J
    Zhang, QY
    [J]. THERMOCHIMICA ACTA, 2003, 404 (1-2) : 3 - 7
  • [10] Study of the microstructure resulting from brazed aluminium materials used in heat exchangers
    Lacaze, J
    Tierce, S
    Lafont, MC
    Thebault, Y
    Pébère, N
    Mankowski, G
    Blanc, C
    Robidou, H
    Vaumousse, D
    Daloz, D
    [J]. MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2005, 413 : 317 - 321