Synthesis and Upconversion Luminescence Properties of CaF2:Yb3+/Tm3+ Microspheres

被引:4
作者
Jiang, Tao [1 ]
Zhao, Dan [1 ]
Qin, Weiping [1 ]
机构
[1] Jilin Univ, Coll Elect Sci & Engn, State Key Lab Integrated Optoelect, Changchun 130012, Peoples R China
基金
国家高技术研究发展计划(863计划); 中国国家自然科学基金;
关键词
CaF2; Microspheres; Upconversion; Nanoparticles; Size Effect; HYDROTHERMAL SYNTHESIS; CDSE NANOCRYSTALLITES; HYDROXIDE NANORODS; NANOWIRES; PHOTOLUMINESCENCE; NANOPARTICLES; NANOTUBES; COMPLEXES; LA(OH)(3); NANOBELTS;
D O I
10.1166/jnn.2011.5253
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
CaF2:Yb3+/Tm3+ microspheres were synthesized by using a simple hydrothermal method. Their structures and morphologies were characterized by X-ray diffraction (XRD) and field-effective scanning electron microscopy (FESEM). The microspheres were formed from a large number of nanospheres with almost the same diameter after annealing. The growth mechanism of the microspheres was discussed. Strong ultraviolet (UV) and blue upconversion (UC) emission from the CaF2 microspheres was observed under 980 nm excitation. The enhancement of the UV UC emission was attributed to the size effect of the nanoscale particles.
引用
收藏
页码:9916 / 9919
页数:4
相关论文
共 24 条
[1]   Shape-controlled synthesis of colloidal platinum nanoparticles [J].
Ahmadi, TS ;
Wang, ZL ;
Green, TC ;
Henglein, A ;
ElSayed, MA .
SCIENCE, 1996, 272 (5270) :1924-1926
[2]   Semiconductor nanocrystals as fluorescent biological labels [J].
Bruchez, M ;
Moronne, M ;
Gin, P ;
Weiss, S ;
Alivisatos, AP .
SCIENCE, 1998, 281 (5385) :2013-2016
[3]   Controllable chemical reaction synthesis of Tb(OH)3 nanorods and their photoluminescence property [J].
Du, Ning ;
Zhang, Hui ;
Ma, Xiangyang ;
Li, DongSheng ;
Yang, Deren .
MATERIALS LETTERS, 2009, 63 (13-14) :1180-1182
[4]   Systematic synthesis and characterization of single-crystal lanthanide orthophosphate nanowires [J].
Fang, YP ;
Xu, AW ;
Song, RQ ;
Zhang, HX ;
You, LP ;
Yu, JC ;
Liu, HQ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (51) :16025-16034
[5]   Hydrothermal synthesis of rare earth (Tb, Y) hydroxide and oxide nanotubes [J].
Fang, YP ;
Xu, AW ;
You, LP ;
Song, RQ ;
Yu, JC ;
Zhang, HX ;
Li, Q ;
Liu, HQ .
ADVANCED FUNCTIONAL MATERIALS, 2003, 13 (12) :955-960
[6]   Interactions of lanthanide complexes with oxidized single-walled carbon nanotubes [J].
Hemraj-Benny, T ;
Banerjee, S ;
Wong, SS .
CHEMISTRY OF MATERIALS, 2004, 16 (10) :1855-1863
[7]   La(OH)3 and La2O3 nanobelts -: Synthesis and physical properties [J].
Hu, Chenguo ;
Liu, Hong ;
Dong, Wenting ;
Zhang, Yiyi ;
Bao, Gang ;
Lao, Changshi ;
Wang, Zhong L. .
ADVANCED MATERIALS, 2007, 19 (03) :470-+
[8]   Crystalline nanowires of Ln2O2S, Ln2O2S2, LnS2 (Ln = la, nd), and La2O2S:EU3+.: Conversions via the boron-sulfur method that preserve shape [J].
Huang, Yi-Zhi ;
Chen, Ling ;
Wu, Li-Ming .
CRYSTAL GROWTH & DESIGN, 2008, 8 (02) :739-743
[9]   Comparison of Ultraviolet Upconversion Luminescence Between Thin Film and Bulk of Calcium Fluoride Co-Doped with Yb3+/Tm3+ Ions [J].
Jiang, Tao ;
Qin, Weiping ;
Ding, Fuheng .
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2010, 10 (03) :2013-2016
[10]   Hydrothermal synthesis and characterization of YVO4 and YVO4:Eu3+ nanobelts and polyhedral micron crystals [J].
Li, Guicun ;
Chao, Kun ;
Peng, Hongrui ;
Chen, Kezheng .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (16) :6228-6231