Enantioselective inclusion in bile acids: resolution of cyclic ketones

被引：28
作者：
Bertolasi, V [1 ]
Bortolini, O [1 ]
Fogagnolo, M [1 ]
Fantin, G [1 ]
Pedrini, P [1 ]
机构：
[1] Univ Ferrara, Dipartimento Chim, I-44100 Ferrara, Italy
来源：
TETRAHEDRON-ASYMMETRY | 2001年 / 12卷 / 10期
关键词：
D O I：
10.1016/S0957-4166(01)00243-9
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Cholic and deoxycholic acids were found to form inclusion compounds with various racemic cyclic ketones enabling direct and straightforward enantiomer separation. The X-ray structure of the 2:1 inclusion complex between (-)-bicyclo[3.2.0]-hept-2-en-6-one and cholic acid is reported. (C) 2001 Elsevier Science Ltd. All rights reserved.
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页码：1479 / 1483
页数：5
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