Synthesis and crystal structure of octakis(dimethyl sulfoxide)lanthanum(III) undecaiodotetramercurate(II)

被引：0
|
作者：
Cherkasova, TG [1 ]
Anosova, YV [1 ]
Shevchenko, TM [1 ]
机构：
[1] Kuzbass State Tech Univ, Kemerovo, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2004年 / 49卷 / 01期
关键词：
D O I：
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中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The new complex octakis(dimethyl sulfoxide)lanthanum(III) undecaiodotetramercurate(II) [La(DMSO)(8)][Hg4I11] (I), where DMSO is CH3SOCH3, is synthesized and structurally characterized. Crystals I are monoclinic: a = 22.425(7) Angstrom, b = 12.542(4) Angstrom, c = 11.548(4) Angstrom alpha = 90degrees, beta = 101.93(2)degrees, gamma = 90degrees, V = 3177.9(18) Angstrom(3), Z = 2, rho(calc) = 3.096 g/cm(3). The lanthanum coordination polyhedron is a distorted square antiprism; mercury has a tetrahedral environment.
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页码：18 / 21
页数：4
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