Preparation and Dewatering Property of Two Sludge Conditioners Chitosan/AM/AA and Chitosan/AM/AA/DMDAAC

被引:16
作者
Fan, Jie [1 ]
Chen, Qiu [1 ]
Li, Jun [1 ]
Wang, Danfeng [1 ]
Zheng, Ran [1 ]
Gu, Qiang [1 ]
Zhang, Yumin [1 ]
机构
[1] Jilin Univ, Coll Chem, Changchun 130012, Jilin, Peoples R China
关键词
Chitosan-grafting copolymer; Synthesis; Flocculation and aggregation; Sludge dewatering; Amphoteric flocculant; GRAFT-POLYACRYLAMIDE FLOCCULANTS; STARCH-BASED FLOCCULANTS; ACRYLIC-ACID; COPOLYMERIZATION; PERFORMANCE; WATER; POLYMERIZATION; IRRADIATION; REMOVAL; SALT;
D O I
10.1007/s10924-018-1342-0
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Two new chitosan-grafting copolymers (chitosan-g-PAM-AA and C-chitosan-g-PAM-AA) as sludge conditioners (flocculation and aggregation) have been prepared by employing ceric sulfate as a free radical initiator under nitrogen atmosphere in aqueous solution. The optimum condition for synthesizing chitosan-grafting copolymer was determined by orthogonal experiments. The structure, morphology and property of the obtained graft polymers were characterized by FT-IR, XRD, SEM, TGA and contact angle. Further, the municipal activated sludge dewatering performance of the synthesized copolymers was evaluated by the filter cake moisture content. Herein, the effects of pH value and dewatering temperatures of activated sludge, loading dosage or cationic degree of C-chitosan-g-PAM-AA on the filter cake moisture content were investigated. The synthesized amphoteric flocculant C-chitosan-g-PAM-AA showed a highly effective flocculation capability for activated sludge compared with chitosan-g-PAM-AA, chitosan, polyacrylamide (PAM). Also, the lowest filter cake moisture content was up to 61.41%.
引用
收藏
页码:275 / 285
页数:11
相关论文
共 58 条
[1]   Design of amphoteric chitosan flocculants for phosphate and turbidity removal in wastewater [J].
Agbovi, Henry K. ;
Wilson, Lee D. .
CARBOHYDRATE POLYMERS, 2018, 189 :360-370
[2]   An Investigation of the Flocculation Characteristics of Polyacrylamide-Grafted Chitosan [J].
Ali, S. K. Akbar ;
Singh, Ram Prakash .
JOURNAL OF APPLIED POLYMER SCIENCE, 2009, 114 (04) :2410-2414
[3]  
ARGUELLESMONAL W, 1988, MAKROMOL CHEM-RAPID, V9, P693
[4]   Polymeric Branched Flocculant Effect on the Flocculation Process of Pulp Suspensions in the Papermaking Industry [J].
Blanco, Angeles ;
Fuente, Elena ;
Concepcion Monte, M. ;
Cortes, Noelia ;
Negro, Carlos .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2009, 48 (10) :4826-4836
[5]   Effect of polyelectrolyte structural features on flocculation behavior: Cationic polysaccharides vs. synthetic polycations [J].
Bratskaya, S ;
Schwarz, S ;
Laube, J ;
Liebert, T ;
Heinze, T ;
Krentz, O ;
Lohmann, C ;
Kulicke, WM .
MACROMOLECULAR MATERIALS AND ENGINEERING, 2005, 290 (08) :778-785
[6]   Evaluation of the starch-based flocculants on flocculation of hairwork wastewater [J].
Du, Qing ;
Wei, Hua ;
Li, Aimin ;
Yang, Hu .
SCIENCE OF THE TOTAL ENVIRONMENT, 2017, 601 :1628-1637
[7]  
DUNG P, 1994, CARBOHYD POLYM, V24, P209, DOI DOI 10.1016/0144-8617(94)90132-5
[8]   Chitosan enhanced coagulation of algal turbid waters - Comparison between rapid mix and ultrasound coagulation methods [J].
Fast, Sara Ann ;
Kokabian, Bahareh ;
Gude, Veera Gnaneswar .
CHEMICAL ENGINEERING JOURNAL, 2014, 244 :403-410
[9]   The thermal degradation of some alkali metal salts of poly(itaconic acid) [J].
Filipovic, JM ;
Katsikas, L ;
Popovic, IG ;
Velickovic, SJ ;
Djakov, TA ;
PetrovicDjakov, DM .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 1997, 49 (01) :335-341
[10]   Graft copolymerization of chitosan with acrylic acid under microwave irradiation and its water absorbency [J].
Ge Huacai ;
Pang Wan ;
Luo Dengke .
CARBOHYDRATE POLYMERS, 2006, 66 (03) :372-378