Synthesis and characterisation of bio-based polyester materials from vegetable oil and short to long chain dicarboxylic acids

被引：44

作者：

Gobin, Maelle ^{[1
,2
]}

Loulergue, Patrick ^{[1
,2
]}

Audic, Jean-Luc ^{[1
,2
]}

Lemiegre, Loic ^{[1
,2
]}

机构：

[1] CNRS, Ecole Natl Super Chim Rennes, UMR 6226, F-35708 Rennes 7, France

[2] Univ Europeenne Bretagne, Rennes, France

来源：

INDUSTRIAL CROPS AND PRODUCTS | 2015年 / 70卷

关键词：

Bio-based polyesters; Epoxidation; Epoxidized vegetable oil; Broccoli seed oil; EPOXIDIZED SOYBEAN OIL; RENEWABLE RAW-MATERIALS; EPOXY-RESINS; PLANT OILS; RESOURCES; BEHAVIOR;

D O I：

10.1016/j.indcrop.2015.03.041

中图分类号：

S2 [农业工程];

学科分类号：

0828 ;

摘要：

Polyester-type polymers were efficiently prepared from broccoli seed oil and several carboxylic diacids. The polyesters were prepared through a simple two-step process including oxidation of the insaturations to oxiranes followed by ring opening with dicarboxylic acids under basic conditions. Eight polymer materials derived from different fatty diacids (from 5 C to 16 C) and an aromatic diacid were prepared and characterised. Rubber-type crosslinked biobased materials exhibited low T-g values comprised between -5 and +5 degrees C depending on the diacid type and length. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：213 / 220

页数：8

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