A novel Ni/Na - Containing inorganic-organic hybrid supramolecule based on polyoxometalate and EDTA with ultraviolet-visible light photochromism

被引：10
作者：
Xiao, Han-Xi [1 ]
Teng, Chun-Lin [1 ]
Cai, Qing [2 ]
Sun, Su-Qin [1 ]
Cai, Tie-Jun [1 ]
Deng, Qian [1 ]
机构：
[1] Hunan Univ Sci & Technol, Minist Educ, Key Lab Theoret Organ Chem & Funct Mol, Xiangtan 411201, Peoples R China
[2] CUNY, Dept Chem, New York, NY 10016 USA
来源：
SOLID STATE SCIENCES | 2016年 / 58卷
关键词：
Polyoxometalates; Supramolecule; EDTA; Inorganic-organic hybrid; Crystal structure; Photochromism; MULTILAYER FILMS; COLORATION; CRYSTAL; NANOPARTICLE; MEMORIES; COMPLEX;
D O I：
10.1016/j.solidstatesciences.2016.06.005
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel Ni/Na - containing inorganic-organic hybrid supramolecule {(PW12O40)center dot[Na-2(NiH(2)EDTA center dot H2O)(H(4)EDTA)center dot 2H(2)O]center dot 2H(2)O center dot H3O}(n) (short for NiEDTA-PW12) has been successfully synthesized by solution method, and investigated by thermogravimetric-differential thermal analysis (TG-DTA), ultraviolet visible (UV-Vis) spectroscopy, cyclic voltammetry (CV), photoluminescence (PL), ultraviolet visible diffuse reflectance spectrum (UV-vis DRS) and single-crystal X-ray diffraction (XRD). NiEDTA-PW12 exhibits intriguing infinite supramolecular structure with Na+ ions as linker. Furthermore, NiEDTA-PW12 displays a fast-responsive reversible photochromism under ultraviolet or visible light. The photochromic property of NiEDTA-PW12 has been investigated by techniques of UV-vis DRS and PL, and the impact of the O-2 on fading of the colored NiEDTA-PW12 has been investigated. (C) 2016 Elsevier Masson SAS. All rights reserved.
引用
收藏
页码：122 / 128
页数：7
相关论文
共 33 条
  • [1] A new double-Keggin-anion-templated organic-inorganic hybrid architecture: Synthesis, crystal structure and photoluminescence
    An, Haiyan
    Xu, Tieqi
    Zheng, Hui
    Han, Zhengbo
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2010, 13 (02) : 302 - 305
  • [2] Spiropyrans and spirooxazines for memories and switches
    Berkovic, G
    Krongauz, V
    Weiss, V
    [J]. CHEMICAL REVIEWS, 2000, 100 (05) : 1741 - 1753
  • [3] Synthesis, properties and crystal structure of some polyoxometallates containing the tris(hydroxymethyl)aminomethane cation
    Bi, LH
    Wang, EB
    Xu, L
    Huang, RD
    [J]. INORGANICA CHIMICA ACTA, 2000, 305 (02) : 163 - 171
  • [4] CYCLIC AND DIFFERENTIAL PULSE VOLTAMMETRIC BEHAVIOR OF REACTANTS CONFINED TO ELECTRODE SURFACE
    BROWN, AP
    ANSON, FC
    [J]. ANALYTICAL CHEMISTRY, 1977, 49 (11) : 1589 - 1595
  • [5] Microwave radiation solid-phase synthesis of phosphotungstate nanoparticle catalysts and photocatalytic degradation of formaldehyde
    Deng, Qian
    Zhou, Wenhui
    Li, Xiaomei
    Peng, Zhenshan
    Jiang, Shaoliang
    Yue, Ming
    Cai, Tiejun
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 262 (1-2) : 149 - 155
  • [6] Kinetics of Coloration in Photochromic Organoammonium Polyoxomolybdates
    Dessapt, Remi
    Collet, Mathieu
    Coue, Violaine
    Bujoli-Doeuff, Martine
    Jobic, Stephane
    Lee, Changhoon
    Whangbo, Myung-Hwan
    [J]. INORGANIC CHEMISTRY, 2009, 48 (02) : 574 - 580
  • [7] Functionalized polyoxometalates with covalently linked bisphosphonate, N-donor or carboxylate ligands: from electrocatalytic to optical properties
    Dolbecq, Anne
    Mialane, Pierre
    Secheresse, Francis
    Keita, Bineta
    Nadjo, Louis
    [J]. CHEMICAL COMMUNICATIONS, 2012, 48 (67) : 8299 - 8316
  • [8] Tuning the Photochromic Properties of Molybdenum Bisphosphonate Polyoxometalates
    El Moll, Hani
    Dolbecq, Anne
    Mbomekalle, Israel Martyr
    Marrot, Jerome
    Deniard, Philippe
    Dessapt, Remi
    Mialane, Pierre
    [J]. INORGANIC CHEMISTRY, 2012, 51 (04) : 2291 - 2302
  • [9] Photochromism in composite and hybrid materials based on transition-metal oxides and polyoxometalates
    He, Tao
    Yao, Jiannian
    [J]. PROGRESS IN MATERIALS SCIENCE, 2006, 51 (06) : 810 - 879
  • [10] Diarylethenes for memories and switches
    Irie, M
    [J]. CHEMICAL REVIEWS, 2000, 100 (05) : 1685 - 1716
1234