A Chitosan Derivative Containing Both Carboxylic Acid and Quaternary Ammonium Moieties for the Synthesis of Cyclic Carbonates

被引：30

作者：

Besse, Vincent ^{[1
,2
]}

Illy, Nicolas ^{[1
,3
]}

David, Ghislain ^{[1
]}

Caillol, Sylvain ^{[1
]}

Boutevin, Bernard ^{[1
]}

机构：

[1] Univ Montpellier, CNRS, Inst Charles Gerhardt Montpellier, UMR 5253,ENSCM, 8 Rue Ecole Normale, F-34296 Montpellier 5, France

[2] COLAS SA, 7 Pl Rene Clair, F-92653 Boulogne, France

[3] Univ Paris 06, CNRS, Inst Parisien Chim Mol, Equipe Chim Polymeres, 4 Pl Jussieu, F-75005 Paris, France

来源：

CHEMSUSCHEM | 2016年 / 9卷 / 16期

关键词：

chitosan; cyclic carbonates; epoxides; heterogeneous catalysis; supported catalyst; CHEMICAL FIXATION; EFFICIENT SYNTHESIS; IONIC LIQUIDS; CATALYTIC FIXATION; HIGHLY EFFICIENT; HYBRID CATALYST; CO2; EPOXIDES; DIOXIDE; CYCLOADDITION;

D O I：

10.1002/cssc.201600499

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chitosan, a renewable feedstock, is modified and used as a catalytic support in the presence of potassium iodide. The system is highly efficient towards the incorporation of carbon dioxide (CO2) into epoxides. It demonstrates very good thermal stability and is recyclable more than five times without loss of activity. The optimal reaction conditions were determined using allylglycidyl ether as a model and extended to a wide range of other epoxides. Cyclic carbonates were obtained with very high yield in a few hours under mild conditions (2-7bar approximate to 0.2-0.7MPa, 80 degrees C) and no solvent.

引用

页码：2167 / 2173

页数：7

共 68 条

[1] Chitosan derivatives obtained by chemical modifications for biomedical and environmental applications [J].

Alves, N. M. ;

Mano, J. F. .

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2008, 43 (05) :401-414

[2] Synthesis of bifunctional cyclic carbonates from CO2 catalysed by choline-based systems [J].

Amaral, Aderito J. R. ;

Coelho, Jorge F. J. ;

Serra, Armenio C. .

TETRAHEDRON LETTERS, 2013, 54 (40) :5518-5522

[3] Multilayered Supported Ionic Liquids as Catalysts for Chemical Fixation of Carbon Dioxide: A High-Throughput Study in Supercritical Conditions [J].

Aprile, Carmela ;

Giacalone, Francesco ;

Agrigento, Paola ;

Liotta, Leonarda F. ;

Martens, Johan A. ;

Pescarmona, Paolo P. ;

Gruttadauria, Michelangelo .

CHEMSUSCHEM, 2011, 4 (12) :1830-1837

[4] Utilisation of CO2 as a chemical feedstock:: opportunities and challenges [J].

Aresta, Michele ;

Dibenedetto, Angela .

DALTON TRANSACTIONS, 2007, (28) :2975-2992

[5] How to explain low molar masses in PolyHydroxyUrethanes (PHUs) [J].

Besse, Vincent ;

Camara, Fatoumata ;

Mechin, Francoise ;

Fleury, Etienne ;

Caillol, Sylvain ;

Pascault, Jean-Pierre ;

Boutevin, Bernard .

EUROPEAN POLYMER JOURNAL, 2015, 71 :1-11

[6] Synthesis and applications of unsaturated cyclocarbonates [J].

Besse, Vincent ;

Camara, Fatou ;

Voirin, Coline ;

Auvergne, Remi ;

Caillol, Sylvain ;

Boutevin, Bernard .

POLYMER CHEMISTRY, 2013, 4 (17) :4545-4561

[7] Synthesis of isosorbide based polyurethanes: An isocyanate free method [J].

Besse, Vincent ;

Auvergne, Remi ;

Carlotti, Stephane ;

Boutevin, Gilles ;

Otazaghine, Belkacem ;

Caillol, Sylvain ;

Pascault, Jean-Pierre ;

Boutevin, Bernard .

REACTIVE & FUNCTIONAL POLYMERS, 2013, 73 (03) :588-594

[8] An Efficient Nonisocyanate Route to Polyurethanes via Thiol-Ene Self-Addition [J].

Calle, Mariola ;

Lligadas, Gerard ;

Ronda, Juan C. ;

Galia, Marina ;

Cadiz, Virginia .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2014, 52 (21) :3017-3025

[9]

Carothers W.H., 1933, J AM CHEM SOC, V55, P5043

[10] Synthesis of Cyclic Carbonates from Polyols and Carbon Dioxide, Urea or Carbon Monoxide [J].

Castro-Osma, Jose A. ;

North, Michael .

CURRENT GREEN CHEMISTRY, 2014, 1 (03) :257-272

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