A Comprehensive Population Balance Model of Emulsion Polymerisation for PSD & MWD: Comparison to Experimental data

被引：0

作者：

Sweetman, S. J. ^{[1
]}

Immanuel, C. D. ^{[1
]}

Malik, T. I. ^{[2
]}

Emmett, S. ^{[3
]}

Williams, N. ^{[3
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem Engn & Chem Technol, Ctr Proc Syst Engn, London SW7 2AZ, England

[2] ICI Wilton Appl Res Grp, Newcastle Upon Tyne, Tyne & Wear, England

[3] ICI Paints, Slough, Berks, England

来源：

18TH EUROPEAN SYMPOSIUM ON COMPUTER AIDED PROCESS ENGINEERING | 2008年 / 25卷

关键词：

Population Balance; Emulsion Polymerisation; PSD; MWD; Validation;

D O I：

暂无

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

A population balance model for emulsion polymerisation has been developed. This model captures PSD and MWD, both of which are key performance indicators for the end latex product. The model employs purely mechanistic kernels and is aimed at maximising predictive capacity. The model is validated against a multi-objective experimental target. The aim is to predict data for PSD, solids, particle number as well as global molecular weight. The experimental system investigated is a vinyl acetate/butyl acrylate copolymerisation with ionic emulsifier and thermal initiator. The predictive capacity is tested by tuning the model to one set of experimental data, then trying to predict results from a further perturbed experiment, with no further tuning. The results of this study indicate that the model is able to capture the main process trends as well as providing an accurate representation of quantitative data.

引用

页码：805 / 810

页数：6

共 17 条

[11] Experimental validation of a 2-D population balance model for spray coating processes
Li, Jianfeng
Freireich, Ben J.
Wassgren, Carl R.
Litster, James D.
CHEMICAL ENGINEERING SCIENCE, 2013, 95 : 360 - 365
[12] Comparison between a computational seated human model and experimental verification data
Olesen, Christian G.
de Zee, Mark
Rasmussen, John
APPLIED BIONICS AND BIOMECHANICS, 2014, 11 (04) : 175 - 183
[13] Modeling and simulation of mixing in water-in-oil emulsion flow through a valve-like element using a population balance model
Favero, Jovani L.
Silva, Luiz Fernando L. R.
Lage, Paulo L. C.
COMPUTERS & CHEMICAL ENGINEERING, 2015, 75 : 155 - 170
[14] Comparison of breakup and coalescence kernels in population balance model for modeling isothermal gas-liquid flow
Ma, Yue
Hu, Guang
Zhang, Huang
Liu, Qianfeng
NUCLEAR ENGINEERING AND DESIGN, 2022, 388
[15] Bioconcentration of gaseous organic chemicals in plant leaves: Comparison of experimental data with model predictions
Polder, MD
Hulzebos, EM
Jager, DT
ENVIRONMENTAL TOXICOLOGY AND CHEMISTRY, 1998, 17 (05) : 962 - 968
[16] A comparison of model order reduction techniques for a four-dimensional population balance model describing multi-component wet granulation processes
Barrasso, Dana
Ramachandran, Rohit
CHEMICAL ENGINEERING SCIENCE, 2012, 80 : 380 - 392
[17] A novel parabolic trough solar collector model - Validation with experimental data and comparison to Engineering Equation Solver (EES)
Behar, Omar
Khellaf, Abdallah
Mohammedi, Kamal
ENERGY CONVERSION AND MANAGEMENT, 2015, 106 : 268 - 281

← 1 2 →