Ion-molecular reactions of free ethylsilicenium ions with alcohols in the gas phase

被引：0
|
作者：
Kochina, TA [1 ]
Shchukin, EV
Nefedov, VD
Sinotova, EN
机构：
[1] Russian Acad Sci, Inst Silicate Chem, St Petersburg, Russia
[2] St Petersburg State Univ, St Petersburg 198904, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2000年 / 70卷 / 06期
关键词：
D O I：
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Ion-molecular reactions of free ethylsilicenium ions with methanol and isobutanol in the gas phase were studied radiochemically. Within the reaction time the ethylsilicenium ion completely isomerizes into the dimethylsilicenium ion. The reaction mechanism was suggested.
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页码：885 / 888
页数：4
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