Rhodium-catalyzed asymmetric conjugate alkynylation of nitroalkenes

被引：32

作者：

Nishimura, Takahiro ^{[1
]}

Sawano, Takahiro ^{[1
]}

Tokuji, Sumito ^{[1
]}

Hayashi, Tamio ^{[1
]}

机构：

[1] Kyoto Univ, Dept Chem, Grad Sch Sci, Sakyo Ku, Kyoto 6068502, Japan

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 36期

关键词：

ENANTIOSELECTIVE MICHAEL ADDITION; DOPAMINE BETA-HYDROXYLASE; TERMINAL ALKYNES; 1,3-DICARBONYL COMPOUNDS; CARBONYL GROUPS; ATOM ECONOMY; KETONES; 1,4-ADDITION; NITROOLEFINS; ALDEHYDES;

D O I：

10.1039/c0cc02181d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Asymmetric addition of (triisopropylsilyl)acetylene to nitroalkenes took place in the presence of a rhodium/chiral bisphosphine catalyst to give beta-alkynylated nitroalkanes in high yields with high enantioselectivity.

引用

页码：6837 / 6839

页数：3

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