High pressure antiferrodistortive phase transition in mixed crystals of EuTiO3 and SrTiO3

被引:4
作者
Parisiades, Paraskevas [1 ,2 ]
Saltarelli, Francesco [3 ]
Liarokapis, Efthymios [4 ]
Koehler, Juergen [5 ]
Bussmann-Holder, Annette [5 ]
机构
[1] Univ Paris 07, CNRS, UMR 7162, Lab Mat & Phenomenes Quant, Paris 13, France
[2] European Synchrotron Radiat Facil, Beamline ID27, 71 Ave Martyrs, F-38000 Grenoble, France
[3] Sapienza Univ Rome, Dept Phys, Piazzale Aldo Moro 5, I-00185 Rome, Italy
[4] Natl Tech Univ Athens, Dept Phys, GR-15780 Athens, Greece
[5] Max Planck Inst Solid State Res, Heisenbergstr 1, D-70569 Stuttgart, Germany
关键词
110 DEGREES K; POWDER DIFFRACTION; MAGNETIC-STRUCTURE;
D O I
10.1063/1.4954819
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
We report a detailed high pressure study on Eu1-xSrxTiO3 polycrystalline samples using synchrotron x-ray diffraction. We have observed a second-order antiferrodistortive phase transition for all doping levels which corresponds to the transition that has been previously explored as a function of temperature. The analysis of the compression mechanism by calculating the lattice parameters, spontaneous strains and tilt angles of the TiO6 octahedra leads to a high pressure phase diagram for Eu1-xSrxTiO3. (C) 2016 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
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页数:7
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