Borohydride complexes of rare earths, and their applications in various organic transformations

被引：97

作者：

Visseaux, Marc ^{[1
]}

Bonnet, Fanny ^{[1
]}

机构：

[1] Univ Lille Nord France, UCCS, CNRS, UMR 8181,ENSCL, Villeneuve Dascq, France

来源：

COORDINATION CHEMISTRY REVIEWS | 2011年 / 255卷 / 3-4期

关键词：

Rare earths; Borohydrides; Tetrahydroborate; Organolanthanides; Polymerization catalysis; RING-OPENING POLYMERIZATION; STEREOSPECIFIC ISOPRENE POLYMERIZATION; CHAIN TRANSFER POLYMERIZATION; RAY CRYSTAL-STRUCTURE; ONE-POT SYNTHESIS; EPSILON-CAPROLACTONE; METHYL-METHACRYLATE; CATALYTIC-ACTIVITY; STRUCTURAL-CHARACTERIZATION; MOLECULAR-STRUCTURE;

D O I：

10.1016/j.ccr.2010.09.016

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Borohydride complexes of the rare earths have attracted increasing interest during the last decade. This review aims to cover recent results over this period with respect to the preparation, characterization, structure, and applications in organic chemistry of this family of compounds, including inorganic and organometallic complexes. Special emphasis is made on their use for polymerization catalysis. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：374 / 420

页数：47

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