Grain Size Engineering of Ferroelectric Zr-doped HfO2 for the Highly Scaled Devices Applications

被引:65
作者
Liao, Jiajia [1 ,2 ]
Zeng, Binjian [1 ,2 ]
Sun, Qi [1 ,2 ]
Chen, Qiang [1 ,2 ]
Liao, Min [1 ,2 ]
Qiu, Chenguang [3 ]
Zhang, Zhiyong [3 ]
Zhou, Yichun [1 ,2 ]
机构
[1] Xiangtan Univ, Key Lab Low Dimens Mat & Applicat Technol, Xiangtan 411105, Peoples R China
[2] Xiangtan Univ, Sch Mat Sci & Engn, Minist Educ, Xiangtan 411105, Peoples R China
[3] Peking Univ, Key Lab Phys & Chem Nanodevices, Beijing 100871, Peoples R China
基金
中国国家自然科学基金;
关键词
Ferroelectric transistors; scaling; Zr-doped HfO2; atomic layer deposition; grain size engineering; THIN-FILMS; DEPOSITION;
D O I
10.1109/LED.2019.2944491
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Ferroelectric Zr-doped HfO2 (HZO) is a promising candidate component for the future transistors and memory devices applications. To address the device-to-device variation in those highly scaled devices, the grain properties of 12-nm-thick HZO films are investigated and optimized by altering the atomic layer deposition (ALD) cycle ratio of HfO2 and ZrO2 at a constant Zr concentration. The largest remanent polarization $2{P}_{r}$ of $41\mu \text{C}$ /cm(2), refined average grain radius from 16.6 nm to 13 nm, and improved grain size distribution with the standard deviation reduced from 5 to 3.3 are realized by adjusting the ALD cycle ratio to 5/5. Furthermore, the possible underlying mechanisms for the ferroelectric behaviors and the growth modes of the HZO films deposited with various cycle ratios are demonstrated.
引用
收藏
页码:1868 / 1871
页数:4
相关论文
共 26 条
[1]   RF-magnetron sputtering deposition of ultra-thin Hf0.5Zr0.5O2 films for non-volatile memory applications [J].
Ambriz-Vargas, F. ;
Nouar, R. ;
Kolhatkar, G. ;
Sarkissian, A. ;
Thomas, R. ;
Gomez-Yanez, C. ;
Gauthier, M. A. ;
Ruediger, A. .
MATERIALS TODAY-PROCEEDINGS, 2017, 4 (07) :7000-7010
[2]  
[Anonymous], 2018, IEEE C 2018 IEEE INT, DOI DOI 10.1109/IEDM.2018.8614682
[3]  
[Anonymous], APPL PHYS LETT
[4]   Ferroelectricity in hafnium oxide thin films [J].
Boescke, T. S. ;
Mueller, J. ;
Braeuhaus, D. ;
Schroeder, U. ;
Boettger, U. .
APPLIED PHYSICS LETTERS, 2011, 99 (10)
[5]   Low-Leakage-Current DRAM-Like Memory Using a One-Transistor Ferroelectric MOSFET With a Hf-Based Gate Dielectric [J].
Cheng, Chun-Hu ;
Chin, Albert .
IEEE ELECTRON DEVICE LETTERS, 2014, 35 (01) :138-140
[6]  
Dunkel S., 2017, 2017 IEEE International Electron Devices Meeting (IEDM), p19.7.1, DOI 10.1109/IEDM.2017.8268425
[7]   Surface morphology and crystallinity control in the atomic layer deposition (ALD) of hafnium and zirconium oxide thin films [J].
Hausmann, DM ;
Gordon, RG .
JOURNAL OF CRYSTAL GROWTH, 2003, 249 (1-2) :251-261
[8]   Variation Caused by Spatial Distribution of Dielectric and Ferroelectric Grains in a Negative Capacitance Field-Effect Transistor [J].
Kao, Ming-Yen ;
Sachid, Angada B. ;
Lin, Yen-Kai ;
Liao, Yu-Hung ;
Agarwal, Harshit ;
Kushwaha, Pragya ;
Duarte, Juan Pablo ;
Chang, Huan-Lin ;
Salahuddin, Sayeef ;
Hu, Chenming .
IEEE TRANSACTIONS ON ELECTRON DEVICES, 2018, 65 (10) :4652-4658
[9]   Grain size engineering for ferroelectric Hf0.5Zr0.5O2 films by an insertion of Al2O3 interlayer [J].
Kim, Han Joon ;
Park, Min Hyuk ;
Kim, Yu Jin ;
Lee, Young Hwan ;
Jeon, Woojin ;
Gwon, Taehong ;
Moon, Taehwan ;
Do Kim, Keum ;
Hwang, Cheol Seong .
APPLIED PHYSICS LETTERS, 2014, 105 (19)
[10]   Ferroelectric Hf0.5Zr0.5O2 Thin Films: A Review of Recent Advances [J].
Kim, Si Joon ;
Mohan, Jaidah ;
Summerfelt, Scott R. ;
Kim, Jiyoung .
JOM, 2019, 71 (01) :246-255