Crystal Structure and Optical Properties of New Hybrid Halobismuthates of 2,2'-Bipyridinium Derivatives

被引：3

作者：

Balabanova, S. P. ^{[1
]}

Buikin, P. A. ^{[1
,2
,3
]}

Ilyukhin, A. B. ^{[2
]}

Rudenko, A. Yu ^{[4
]}

Dorovatovskii, P., V ^{[5
]}

Korlyukov, A. A. ^{[3
]}

Kotov, V. Yu ^{[1
,2
]}

机构：

[1] Natl Res Univ Higher Sch Econ, Moscow 101000, Russia

[2] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

[3] Russian Acad Sci, Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia

[4] Russian Acad Sci, Zelinsky Inst Organ Chem, Moscow 119991, Russia

[5] Kurchatov Inst, Natl Res Ctr, Moscow 123182, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2022年 / 67卷 / 07期

关键词：

hybrid halobismuthates; crystal structure; band gap; POLYNUCLEAR HALIDE-COMPLEXES; BISMUTH COMPLEXES; CHARGE-TRANSFER; IODOBISMUTHATE; PEROVSKITES; SALTS;

D O I：

10.1134/S0036023622070038

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New hybrid 2,2'-bipyridinium halobismuthates ([bipyH](+)) (I and II), 7,8-dihydro-6H-dipyrido[1,2-a:2',1'-c][1,4]diazepine-5,9-diium ([bipyC(3)](2+)) (III), 6,7,8,9-tetrahydrodipyrido[1,2-a:2',1'-c][1,4]diazocin-5,10-diium ([bipyC(4)](2+)) (IV), and 1,1'-(pentanediyl)bis(2,2'-bipyridinium) ((bipyH)(2)C-5](4+)) (V) have been isolated and characterized by X-ray diffraction. The structure of I contains a monoprotonated cation 2,2'-bipyridinium and the isolated [Bi2Br10](4-) anion. 2,2'-Bipyridinium bromobismuthate II contains a polymeric anion and is isostructural to the previously described iodobismuthate. Bromobismuthate III includes [BiBr6](3-) anions and water molecules. Iodobismuthate [bipyC(3)](2)[Bi2I10] (VI) is isostructural to IV. The structure of V contains [(bipyH)(2)C-5](4+) cations and three types of anions: [Bi2Br10](4-), [BiBr6](3-), and Br-. Compounds I, III, and VI have been isolated in pure form. The values of the optical band gap for them are 2.84, 2.88, and 2.11 eV, respectively.

引用

页码：1018 / 1024

页数：7

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