EFFECT OF EXCESS FREE ENERGY OF THE SOLVENTS ON THE KINETICS OF OXIDATION OF METHIONINE BY NICOTINIUM DICHROMATE

被引：0

作者：

Bhuvaneshwari, D. S. ^{[2
]}

Elango, K. P. ^{[1
]}

机构：

[1] Gandhigram Rural Univ, Dept Chem, Gandhigram 624302, India

[2] PSNA Coll Engn & Technol, Dept Chem, Dindigul 624622, India

来源：

OXIDATION COMMUNICATIONS | 2010年 / 33卷 / 04期

关键词：

solvent effect; kinetics; methionine; TETRAMETHYLAMMONIUM FLUOROCHROMATE; CHROMIUM(VI); PARAMETERS; ANILINES;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The oxidation of methionine by nicotinium dichromate (NDC) has been studied in different classes of water/organic solvent mixtures according to their excess molar free energy function. The rate data are correlated with different solvent parameters using linear multiple regression equations. From the results, information on the solvent-reactants and the solvent transition state interactions is obtained.

引用

页码：878 / 882

页数：5

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