Self-penetrating and interpenetrating 3D metal-organic frameworks constructed from 4-(4-carboxyphenoxy)-phthalic acid and N-donor auxiliary ligands

被引:4
|
作者
Wu, He [1 ]
Sun, Wu-Juan [1 ]
Zhao, Wen-Jie [2 ]
Shi, Ting [1 ]
Liao, Xu-Zhao [1 ]
Yang, Xu-Wu [1 ]
机构
[1] NW Univ Xian, Key Lab Synthet & Nat Funct Mol Chem, Minist Educ, Shaanxi Key Lab Physicoinorgan Chem,Coll Chem & M, Xian 710069, Peoples R China
[2] Xianyang Vocat Tech Coll, Dept Biochem Engn, Xianyang 712000, Peoples R China
关键词
entangled structure; X-ray diffraction; luminescence; thermal analysis; CAMBRIDGE STRUCTURAL DATABASE; COORDINATION POLYMERS; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURES; IN-SITU; NETWORK; DICARBOXYLATE; COMPLEXES; DESIGN; MOTIFS;
D O I
10.1515/chempap-2015-0006
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two new interesting entangled structures, namely, [Ni-1.5(L)(bpy)(2)(H2O)(3)](n) center dot 3nH(2)O (I) and [Cd-3(L)(2)(bbi)(2)](n) center dot nH(2)O (II) (where H3L is 4-(4-carboxyphenoxy)-phthalic acid, bpy is 4,4'-bipyridine, and bbi is 1,1'-(1,4-butanediyl)bis(imidazole)) have been synthesized and characterized by elemental analysis (EA), infrared spectra (IR), X-ray powder diffraction (XRPD), solid fluorescence and thermogravimetric analysis (TGA). Single-crystal X-ray diffraction analysis revealed that complex I possesses a 3D self-penetrating framework constructed from ladder-like and fishbone-like subunits. Complex II shows a 3D framework of two-fold interpenetration assembled from trinuclear Cd(II) clusters bridged by bbi and L3- ligands. (C) 2014 Institute of Chemistry, Slovak Academy of Sciences
引用
收藏
页码:300 / 308
页数:9
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