Ionic liquid solubilized boranes as hypergolic fluids

被引：63

作者：

Gao, Haixiang ^{[1
]}

Shreeve, Jean'ne M. ^{[2
]}

机构：

[1] China Agr Univ, Dept Appl Chem, Beijing 100094, Peoples R China

[2] Univ Idaho, Dept Chem, Moscow, ID 83844 USA

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2012年 / 22卷 / 22期

关键词：

CHEMICAL HYDROGEN STORAGE; DICYANAMIDE ANION; AMMONIA-BORANE; NITRIC-ACID; FUELS; SALTS; MECHANISM; IGNITION;

D O I：

10.1039/c2jm31627g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Borane compounds which are hydrogen storage materials are hypergolic with white fuming nitric acid as oxidizer. When dissolved in ionic liquids, the borane solutions exhibit ignition delay times which are superior to any known hypergolic ionic liquids. These borane-ionic liquid solutions appear to be the brightest hope so far to replace hydrazine and its derivatives as fuels in hypergolic propellant systems.

引用

页码：11022 / 11024

页数：3

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