Simple unprecedented conversion of phosphine oxides and sulfides to phosphine boranes using sodium borohydride

被引：124

作者：

Rajendran, Kamalraj V. ^{[1
]}

Gilheany, Declan G. ^{[1
]}

机构：

[1] Univ Coll Dublin, Sch Chem & Chem Biol, Ctr Synth & Chem Biol, Dublin 4, Ireland

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 06期

基金：

爱尔兰科学基金会;

关键词：

STEREOSPECIFIC DEOXYGENATION; PHOSPHORUS-COMPOUNDS; SOLID-STATE; REDUCTION; SALTS; TRIPHENYLPHOSPHINE; HEXACHLORODISILANE; STEREOCHEMISTRY; SECONDARY; CENTERS;

D O I：

10.1039/c1cc14856g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A variety of phosphine oxides and sulfides can be efficiently converted directly to the corresponding phosphine boranes using oxalyl chloride followed by sodium borohydride. Optically active P-stereogenic phosphine oxides can be converted stereospecifically to phosphine boranes with inversion of configuration by treatment with Meerwein's salt followed by sodium borohydride.

引用

页码：817 / 819

页数：3

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