Self-powered light-induced plating of metals on crystalline silicon solar cells

被引：2

作者：

Luo, Xiaobin ^{[1
]}

Li, Junjie ^{[1
]}

Chen, Xu ^{[1
]}

Sajjad, Muhammad ^{[1
]}

He, Taoling ^{[1
]}

Li, Xuan ^{[1
]}

Wu, Lijuan ^{[1
]}

Liu, Yongjun ^{[2
]}

Sun, Li ^{[3
,4
]}

Ren, Yang ^{[1
]}

Zhou, Xiaowei ^{[1
]}

Liu, Zhu ^{[1
]}

机构：

[1] Yunnan Univ, Sch Phys Sci & Astron, Kunming 650091, Yunnan, Peoples R China

[2] Yunnan Univ, Adv Anal & Measurement Ctr, Kunming 650091, Yunnan, Peoples R China

[3] Univ Houston, Dept Mech Engn, Houston, TX 77204 USA

[4] Univ Houston, Texas Ctr Superconduct TcSUH, Houston, TX 77204 USA

来源：

SOLAR ENERGY | 2018年 / 173卷

关键词：

Self-powered electrochemical reaction; Electrolyte/Si interface; Light-induced plating; Silicon solar cells; NICKEL; NI; ELECTRODEPOSITION; SILICIDATION; ALLOYS; DEVICE; PACK;

D O I：

10.1016/j.solener.2018.07.044

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Light induced deposition of metallic Zn, Fe, Co, Ni, Bi, and Cu on crystalline Si solar cell cathodes has been studied as a part of developing self-powered devices. The direct metal deposition relies on the relative position of Si Fermi level and the equilibrium potential of the metal/ion and H+/H-2 in electrolyte. Direct deposition of above mentioned metals shows three types of light-induced plating (LIP) behavior. Even with a relative large potential barrier, Cu2+ /Cu and Bi3+ /Bi could be deposited by the induced plating of the hydrogen evolution. The current density of the Co2+/Co and Ni2+/Ni have been reduced by the light absorption of the electrolyte impact on the solar cell. This work demonstrated the Si solar cells can be used to provide self-powered for metal deposition which can be used in the heavy metal treatment for the polluted water.

引用

页码：277 / 282

页数：6

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