Dynamics in Self-assembled Organic Monolayers at the Liquid/Solid Interface Revealed by Scanning Tunneling Microscopy

被引：13

作者：

De Feyter, Steven ^{[1
]}

Xu, Hong ^{[1
]}

Mali, Kunal ^{[1
]}

机构：

[1] KU Leuven Univ Leuven, Dept Chem, Div Mol Imaging & Photon, B-3001 Louvain, Belgium

来源：

CHIMIA | 2012年 / 66卷 / 1-2期

关键词：

Dynamics; HOPG; Scanning tunneling microscopy; Self-assembly; SINGLE-MOLECULE DYNAMICS; SUPRAMOLECULAR ASSEMBLIES; CONFORMATIONAL DYNAMICS; MULTIVALENT HEXAPOD; ACID-DERIVATIVES; SURFACE; MANIPULATION; CHIRALITY; GRAPHITE; ISOMERIZATION;

D O I：

10.2533/chimia.2012.38

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The liquid/solid interface provides an interesting medium for molecular self-assembly and scanning tunneling microscopy is the preferred technique to analyse the structural features of the surface-supported self-assembled monolayers in this medium. An interesting aspect is the phenomenon of molecular dynamics at the liquid/solid interface. In this mini-review, we report on our efforts and strategies to investigate and even induce molecular dynamics at the liquid/solid interface, bringing insight to various kinds of processes such as conformational, translational and adsorption/desorption dynamics.

引用

页码：38 / 43

页数：6

共 61 条

[1] Time evolution analysis of a 2D solid-gas equilibrium:: a model system for molecular adsorption and diffusion [J].

Berner, S ;

Brunner, M ;

Ramoino, L ;

Suzuki, H ;

Güntherodt, HJ ;

Jung, TA .

CHEMICAL PHYSICS LETTERS, 2001, 348 (3-4) :175-181

[2]

Böhringer M, 1999, ANGEW CHEM INT EDIT, V38, P821, DOI 10.1002/(SICI)1521-3773(19990315)38:6<821::AID-ANIE821>3.0.CO

[3]

2-A

[4] Two-dimensional self-assembly of supramolecular clusters and chains [J].

Böhringer, M ;

Morgenstern, K ;

Schneider, WD ;

Berndt, R ;

Mauri, F ;

De Vita, A ;

Car, R .

PHYSICAL REVIEW LETTERS, 1999, 83 (02) :324-327

[5] Chiral ordering and conformational dynamics for a class of oligo-phenylene-ethynylenes on Au(111) [J].

Busse, Carsten ;

Weigelt, Sigrid ;

Petersen, Lars ;

Laegsgaard, Erik ;

Besenbacher, Flemming ;

Linderoth, Trolle R. ;

Thomsen, Anne H. ;

Nielsen, Morten ;

Gothelf, Kurt V. .

JOURNAL OF PHYSICAL CHEMISTRY B, 2007, 111 (21) :5850-5860

[6]

CIESIELSKI A, 2010, ANGEW CHEM INT EDIT, V49, P1

[7] STM investigations of organic molecules physisorbed at the liquid-solid interface [J].

Cyr, DM ;

Venkataraman, B ;

Flynn, GW .

CHEMISTRY OF MATERIALS, 1996, 8 (08) :1600-1615

[8] Scanning tunneling microscopy:: A unique tool in the study of chirality, dynamics, and reactivity in physisorbed organic monolayers [J].

De Feyter, S ;

Gesquière, A ;

Abdel-Mottaleb, MM ;

Grim, PCM ;

De Schryver, FC ;

Meiners, C ;

Sieffert, M ;

Valiyaveettil, S ;

Müllen, K .

ACCOUNTS OF CHEMICAL RESEARCH, 2000, 33 (08) :520-531

[9] Local field controlled switching in a one-dimensional dipolar array [J].

de Jonge, Jeroen J. ;

Ratner, Mark A. ;

de Leeuw, Simon W. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (09) :3770-3777

[10] Synthesis of Well-Ordered COF Monolayers: Surface Growth of Nanocrystalline Precursors versus Direct On-Surface Polycondensation [J].

Dienstmaier, Juergen F. ;

Gigler, Alexander M. ;

Goetz, Andreas J. ;

Knochel, Paul ;

Bein, Thomas ;

Lyapin, Andrey ;

Reichlmaier, Stefan ;

Heckl, Wolfgang M. ;

Lackinger, Markus .

ACS NANO, 2011, 5 (12) :9737-9745

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