Self-matting waterborne fluoropolymers

被引:11
作者
Belen Lopez, Ana [1 ,2 ]
Bohorquez, Silfredo Javier [3 ]
Meeuwisse, Marcel [3 ]
Mestach, Dirk [3 ]
de la Cal, Jose C. [1 ,2 ]
Asua, Jose M. [1 ,2 ]
机构
[1] Univ Basque Country, UPV EHU, Ctr Joxe Mari Korta, POLYMAT, Avda Tolosa 72, Donostia San Sebastian 20018, Spain
[2] Univ Basque Country, UPV EHU, Ctr Joxe Mari Korta, Dept Quim Aplicada,Grp Ingn Quim, Avda Tolosa 72, Donostia San Sebastian 20018, Spain
[3] Allnex, Synthesebaan 1, NL-4612 RB Bergen Op Zoom, Netherlands
关键词
Miniemulsion polymerization; Fluorinated polymers; Waterborne hydrophobic coatings; Matte paints; EMULSION POLYMERIZATION; MINIEMULSIFICATION; COATINGS; ACRYLATE; LATEXES;
D O I
10.1016/j.porgcoat.2017.12.003
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
This work describes a study on the incorporation of waterborne fluoropolymer dispersions into paint formulations to act as a film forming binder for matting purposes. The waterborne fluoropolymer dispersions were prepared employing miniemulsion polymerization, reaching concentrations of 80-100 wt% of the fluorinated polymer in the backbone. Afterwards, different pigmented paints were prepared using the waterborne fluoropolymers as self-matting co-binders. Different strategies were used to incorporate the waterborne fluoropolymers into the paint formulation, which also included the partial substitution of commercial matting agents. The pigmented paints were applied onto different substrates and the matting efficiency evaluated. The results clearly showed that these waterborne fluoropolymers can be used as an alternative replacement for commercial matting agents, while adding value to the coating by offering enhanced hydrophobicity as compared to regular acrylic binders.
引用
收藏
页码:57 / 69
页数:13
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