Mechanistic Studies of Transition Metal-Mediated C-C Bond Activation

被引：0

作者：

Jones, William D. ^{[1
]}

机构：

[1] Univ Rochester, Dept Chem, Rochester, NY 14627 USA

来源：

C-C BOND ACTIVATION | 2014年 / 346卷

关键词：

Activation; Carbon-carbon; Cleavage; Mechanism; Thermodynamics; CARBON-CARBON BOND; ALLYL CYANIDE COMPLEX; REDUCTIVE ELIMINATION; OXIDATIVE ADDITION; PHOSPHINE COMPLEXES; NICKEL-COMPLEXES; CATALYTIC HYDROCYANATION; THEORETICAL-EXAMINATION; ZEROVALENT NICKEL; AROMATIC NITRILES;

D O I：

10.1007/128_2013_491

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Organometallic compounds have been found to be of use in cleaving C-C bonds, as strong metal-carbon bonds can be formed to replace the bond that is broken. Studies of the mechanism of C-C cleavage can provide insight into how these bonds can be cleaved, and can give valuable information that can be used to develop new strategies for breaking C-C bonds and using the products in catalysis. In this chapter, we will examine a number of systems where mechanistic information has been obtained in C-C cleavage.

引用

页码：1 / 31

页数：31

共 70 条

[1]

Abba M., 1997, J. Organomet. Chem, V532, P267

[2]

Acosta-Ramirez A, 2008, J ORGANOMETALLICS, V27, P1834

[3]

Acosta-Ramirez A., 2007, J. Organometallics, V26, P5766

[4]

Acosta-Ramirez A, 2007, J ORGANOMETALLICS, V26, P1712

[5] Study of the reactivity of 2-methyl-3-butenenitrile with Ni(0)-N-heterocyclic carbene complexes [J].

Acosta-Ramirez, Alberto ;

Morales-Morales, David ;

Serrano-Becerra, Juan Manuel ;

Arevalo, Alma ;

Jones, William D. ;

Garcia, Juventino J. .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2008, 288 (1-2) :14-18

[6] Isomerization of 2-methyl-3-butenenitrile with (bis-diphenylphosphinoferrocene)nickel compounds:: Catalytic and structural studies [J].

Acosta-Ramirez, Alberto ;

Munoz-Hernandez, Miguel ;

Jones, William D. ;

Garcia, Juventino J. .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2006, 691 (18) :3895-3901

[7] Experimental and theoretical examination of C-CN bond activation of benzonitrile using zerovalent nickel [J].

Atesin, Tuelay A. ;

Li, Ting ;

Lachaize, Sebastien ;

Garcia, Juventino J. ;

Jones, William D. .

ORGANOMETALLICS, 2008, 27 (15) :3811-3817

[8] Experimental and theoretical examination of C-CN and C-H bond activations of acetonitrile using zerovalent nickel [J].

Atesin, Tulay A. ;

Li, Ting ;

Lachaize, Sebastien ;

Brennessel, William W. ;

Garcia, Juventino J. ;

Jones, William D. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (24) :7562-7569

[9]

ATKINSON ER, 1964, CHEM IND-LONDON, P934

[10] Highly selective hydrocyanation of butadiene toward 3-pentenenitrile [J].

Bini, Laura ;

Mueller, Christian ;

Wilting, Jos ;

von Chrzanowski, Lars ;

Spek, Anthony L. ;

Vogt, Dieter .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (42) :12622-+

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