Retention of Pt→B bonding in oxidative addition reactions of the platinaboratrane [Pt(PPh3){B(mt)3}](Pt→B)10 (mt = methimazolyl)

被引：83

作者：

Crossley, Ian R. ^{[1
]}

Hill, Anthony F. ^{[1
]}

Willis, Anthony C. ^{[1
]}

机构：

[1] Australian Natl Univ, Inst Adv Studies, Res Sch Chem, Canberra, ACT, Australia

来源：

ORGANOMETALLICS | 2008年 / 27卷 / 03期

关键词：

D O I：

10.1021/om700835h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The platinaboratrane [Pt(PPh3){B(mt)(3)}](Pt -> B)(10) (mt = methimazolyl) is prone to oxidative addition reactions with a range of substrates (Cl-2, Br-2, I-2, HCl, CH3I) without disrupting the platinum-boron dative bond, as illustrated by the first structurally characterized platinaboratranes [PtH(PPh3){B(mt)(3)}]Cl(Pt -> B)(8) and [PtI2{B(mt)(3)}](Pt -> B)(8).

引用

页码：312 / 315

页数：4

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