Hydrodynamic screening of star polymers in shear flow

被引:86
作者
Ripoll, M. [1 ]
Winkler, R. G. [1 ]
Gompper, G. [1 ]
机构
[1] Forschungszentrum, Inst Festkorperforsch, D-52425 Julich, Germany
关键词
D O I
10.1140/epje/i2006-10220-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The mutual effects of the conformations of a star polymer in simple shear flow and the deformation of the solvent flow field are investigated by a hybrid mesoscale simulation technique. We characterize the flow field near the star polymer as a function of its functionality (arm number) f . A strong screening of the imposed flow is found inside the star polymer, which increases with increasing f . To elucidate the importance of hydrodynamic screening, we compare results for hydrodynamic and random solvents. The dependence of the polymer orientation angle on the Weissenberg number shows a power law behavior with super-universal exponent --independent of hydrodynamic and excluded-volume interactions. In contrast, the polymer rotation frequency changes qualitatively when hydrodynamic interactions are switched on.
引用
收藏
页码:349 / 354
页数:6
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