Selective nitration of aromatic compounds with bismuth subnitrate and thionyl chloride

被引:39
作者
Muathen, HA [1 ]
机构
[1] Umm Alqura Univ, Dept Chem, Mecca, Saudi Arabia
关键词
bismuth subnitrate; thionyl chloride; nitration; aromatic compounds; phenols;
D O I
10.3390/80700593
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Bismuth subnitrate/thionyl chloride have been found to be an efficient combination of reagents for nitration of a wide range of aromatic compounds in dichloromethane. Phenols, in particular, were easily mononitrated and dinitrated with the reagents by controlling the stoichiometry.
引用
收藏
页码:593 / 598
页数:6
相关论文
共 26 条
[1]   DIPHENYLENES .3. SUBSTITUTION IN THE NUCLEUS [J].
BAKER, W ;
BARTON, JW ;
MCOMIE, JFW .
JOURNAL OF THE CHEMICAL SOCIETY, 1958, (AUG) :2666-2674
[2]   BENZOCYCLO-OCTATETRAENES .2. NITRO DERIVATIVES [J].
BARTON, JW ;
WHITAKER, KE .
JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1968, (13) :1663-&
[3]   Polycyclic aromatic compounds as anticancer agents: Synthesis and biological evaluation of some chrysene derivatives [J].
Becker, FF ;
Banik, BK .
BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, 1998, 8 (20) :2877-2880
[4]   CALCIUM NITRATE - A NEW NITRATING AGENT FOR NUCLEAR NITRATION OF SUBSTITUTED PHENOLS [J].
BISARYA, SC ;
JOSHI, SK ;
HOLKAR, AG .
SYNTHETIC COMMUNICATIONS, 1993, 23 (08) :1125-1137
[5]   A PROCEDURE FOR QUANTITATIVE REGIOSELECTIVE NITRATION OF AROMATIC-HYDROCARBONS IN THE LABORATORY [J].
CORNELIS, A ;
DELAUDE, L ;
GERSTMANS, A ;
LASZLO, P .
TETRAHEDRON LETTERS, 1988, 29 (46) :5909-5912
[6]   CLAY-SUPPORTED REAGENTS .5. NITRATION OF ESTRONE INTO 2-NITROESTRONE BY CLAY-SUPPORTED FERRIC NITRATE [J].
CORNELIS, A ;
LASZLO, P ;
PENNETREAU, P .
JOURNAL OF ORGANIC CHEMISTRY, 1983, 48 (24) :4771-4772
[7]   Vanadium(V) oxytrinitrate, VO(NO3)3.: A powerful reagent for the nitration of aromatic compounds at room temperature under nonacidic conditions [J].
Dove, MFA ;
Manz, B ;
Montgomery, J ;
Pattenden, G ;
Wood, SA .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1998, (10) :1589-1590
[8]   MILD AND SELECTIVE NITRATION BY CLAYCOP [J].
GIGANTE, B ;
PRAZERES, AO ;
MARCELOCURTO, MJ .
JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (11) :3445-3447
[9]   THE SYNTHESIS AND APPLICATION OF NOVEL NITRATING AND NITROSATING AGENTS [J].
HAKIMELAHI, GH ;
SHARGHI, H ;
ZARRINMAYEH, H ;
KHALAFINEZHAD, A .
HELVETICA CHIMICA ACTA, 1984, 67 (03) :906-915
[10]   Stomach-specific anti-H-pylori therapy.: 1:: preparation and characterization of tetracyline-loaded chitosan microspheres [J].
Hejazi, R ;
Amiji, M .
INTERNATIONAL JOURNAL OF PHARMACEUTICS, 2002, 235 (1-2) :87-94