π-π Interaction intercalation of layered carbon materials with metallocene

被引：42
作者：
Gao, Yongjun [1 ,2 ]
Hu, Gang [3 ]
Zhang, Wei [1 ]
Ma, Ding [1 ]
Bao, Xinhe [2 ]
机构：
[1] Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
[2] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
[3] Exponent Inc, Hangzhou 310053, Zhejiang, Peoples R China
来源：
DALTON TRANSACTIONS | 2011年 / 40卷 / 17期
基金：
中国国家自然科学基金;
关键词：
GRAPHITE OXIDE; GRAPHENE; NANOPARTICLES; NANOSHEETS; COMPLEXES; CATALYSTS; FILMS;
D O I：
10.1039/c0dt01392g
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new hybrid material consisting of ferrocene and layered carbon (LC: graphene oxide (GO) or reduced graphene oxide (RGO)) was prepared through a facile intercalation approach. The structure of ferrocene was well maintained while the strong p-p interaction between LC and ferrocene remarkably suppressed the sublimation of ferrocene and promoted ferrocene to decompose into iron nanoparticles in between layers of LC. The hybrid exhibited excellent electrochemical properties in electrocatalytic oxidation of ascorbic acid (AA).
引用
收藏
页码：4542 / 4547
页数：6
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