Radical-mediated aerobic oxidation of substituted styrenes and stilbenes

被引：0

作者：

Aman, Hasil ^{[1
]}

Chiu, Wei-Hua ^{[1
]}

Liu, Pin-Heng ^{[1
]}

Chuang, Gary Jing ^{[1
]}

机构：

[1] Chung Yuan Christian Univ Chungli, Dept Chem, Taoyuan 32023, Taiwan

来源：

NEW JOURNAL OF CHEMISTRY | 2021年 / 45卷 / 43期

关键词：

C DOUBLE-BOND; MOLECULAR-OXYGEN; PHOTOOXIDATIVE CLEAVAGE; METAL-FREE; ALKENES; OLEFINS; EPOXIDATION; ALDEHYDES; EFFICIENT;

D O I：

10.1039/d1nj04755h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A 2,2-azobis(isobutyronitrile)-catalyzed oxidative cleavage of alkenes with molecular oxygen as the oxidant was described. Carbonyl compounds and oxiranes were obtained in moderate yield under mild conditions. This study provided useful insights into the mechanism of aerobic oxidative cleavage of alkenes.

引用

页码：20103 / 20106

页数：4

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