Synthesis and photoluminescent properties of two 2D and 3D iodocuprates modified by a protonated ligand

被引：33
作者：
Song, Jiao [1 ]
Hou, Yajie [1 ]
Zhang, Lifang [1 ]
Fu, Yunlong [1 ]
机构：
[1] Shanxi Normal Univ, Sch Chem & Mat Sci, Linfen 041004, Shanxi, Peoples R China
来源：
CRYSTENGCOMM | 2011年 / 13卷 / 11期
关键词：
METAL-ORGANIC FRAMEWORKS; HYDROTHERMAL SYNTHESIS; CRYSTAL-STRUCTURE; COPPER(I) IODIDE; COORDINATION POLYMERS; SUPERTETRAHEDRAL CLUSTERS; HALIDE; COMPLEXES; TOPOLOGY; CATIONS;
D O I：
10.1039/c1ce05020f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two new cuprous iodides [Cu4I5(DABCOH(+)) CH3CN] (1) and [Cu7I8(DABCOH(+)) DABCO] (2) (DABCO = 1,4-diazabicyclo-[2.2.2] octane) have been prepared solvothermally and characterized by IR, TGA, elemental analysis, powder/single-crystal X-ray diffraction and photoluminescent properties. Compound 1 contains a 2D cuprous iodide layer Cu4I5-, while compound 2 exhibits a novel 3D open framework constructed from [Cu14I16](2-) clusters with six-connected (4(12).6(3)) net, and both of them are modified by monoprotonated DABCO ligand, which may be related with the high-dimensional iodocuprates. 1 and 2 display intense orange emission with maximum at 547 nm and 561 nm, respectively, which are rarely found in the most reported iodocuprates.
引用
收藏
页码：3750 / 3755
页数：6
相关论文
共 50 条
  • [31] Synthesis, crystal structure and photoluminescent property of a novel indium (III) supramolecular 3D framework
    Wang, Liping
    Zhang, Tianbin
    Huang, Liangliang
    Xu, Jianing
    Wang, Gang
    Zhang, Hua
    Wang, Li
    JOURNAL OF MOLECULAR STRUCTURE, 2010, 975 (1-3) : 215 - 219
  • [32] Auxiliary ligand directed two new Zn(II) compounds: from 2D→3D polythreaded framework to 2-fold interpenetrated 3D framework
    Xu, Hong-Na
    Gao, Jing
    Cheng, Yan
    INORGANIC AND NANO-METAL CHEMISTRY, 2021,
  • [33] Anion-Assisted Structural Variation of Cadmium Coordination Polymers: From 2D → 3D Inclined Polycatenation to 2D → 3D Polythreading
    Xu, Bo
    Lue, Jian
    Cao, Rong
    CRYSTAL GROWTH & DESIGN, 2009, 9 (07) : 3003 - 3005
  • [34] Hydrothermal synthesis of zinc(II)-phosphonate coordination polymers with different dimensionality (0D, 2D, 3D) and dimensionality change in the solid phase (0D → 3D) induced by temperature
    Fernandez-Zapico, Eva
    Montejo-Bernardo, Jose
    Fernandez-Gonzalez, Alfonso
    Garcia, Jose R.
    Garcia-Granda, Santiago
    JOURNAL OF SOLID STATE CHEMISTRY, 2015, 225 : 285 - 296
  • [35] Discretization in 2D and 3D orders
    Couprie, M
    Bertrand, G
    Kenmochi, Y
    GRAPHICAL MODELS, 2003, 65 (1-3) : 77 - 91
  • [36] Chiral 3D/3D hetero-interpenetrating framework with six kinds of helices, 3D polyrotaxane and 2D network via one-pot reaction
    Zhang, Ming-Dao
    Di, Chang-Miao
    Qin, Ling
    Yang, Qing-Xiang
    Li, Yi-Zhi
    Guo, Zi-Jian
    Zheng, He-Gen
    CRYSTENGCOMM, 2013, 15 (02): : 227 - 230
  • [37] Synthesis, crystal structures and luminescence properties of two novel 3D heterometallic coordination polymers
    Zhang, Wan-zhong
    Lv, Tian-yi
    Wei, De-zhou
    Xu, Rui
    Xiong, Gang
    Wang, Yu-qi
    Gao, En-jun
    Sun, Ya-guang
    INORGANIC CHEMISTRY COMMUNICATIONS, 2011, 14 (08) : 1245 - 1249
  • [38] An Unusual 2D → 3D Metal-organic Framework Directed by Rigid and Flexible Co-Ligands
    Liu, Jian-Qiang
    Wang, Yao-Yu
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2011, 41 (12) : 1940 - 1944
  • [39] ZnII/CdII-coordination polymers from 1D chain, 2D layer to 3D framework with imidazole-based dicarboxylate ligand
    Dong, Wen-Wen
    Li, Dong-Sheng
    Zhao, Jun
    Wu, Ya-Pan
    Meng, Cai-Xia
    Wang, Yao-Yu
    INORGANICA CHIMICA ACTA, 2012, 384 : 260 - 265
  • [40] 1D chain, 2D layer and trinuclear unit based 3D frameworks of indium(iii)-biphenyl carboxylate complexes
    Xu, Wen-Tao
    Jiang, Fei-Long
    Gao, Qiang
    Wu, Ming-Yan
    Chen, Lian
    Hong, Mao-Chun
    INORGANICA CHIMICA ACTA, 2012, 386 : 36 - 45
12345