Unprecedented mechanochemical preparation of 18Crown[6] and 15Crown[5] adducts of ammonium hydrogen sulfate by grinding or kneading

被引：33
作者：
Braga, D [1 ]
Curzi, M [1 ]
Lusi, M [1 ]
Grepioni, F [1 ]
机构：
[1] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy
来源：
CRYSTENGCOMM | 2005年 / 7卷
关键词：
D O I：
10.1039/b504459f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The complex 18Crown[6].[NH4][HSO4].2H(2)O has been prepared by co-grinding of solid 18Crown[6] ether and solid [NH4][HSO4], while the complex (15Crown[5])(3).[NH4](2)[H3O][HSO4](3).H2O has been obtained by kneading liquid 15Crown[5] together with solid [NH4][HSO4]. Structural characterization has been achieved on single crystals obtained by recrystallization of the solid products from water.
引用
收藏
页码：276 / 278
页数：3
相关论文
共 51 条
[1]   Laying traps for elusive prey: Recent advances in the non-covalent binding of anions [J].
Atwood, JL ;
Holman, KT ;
Steed, JW .
CHEMICAL COMMUNICATIONS, 1996, (12) :1401-1407
[2]   Solvent-free mechanochemical synthesis of phosphonium salts [J].
Balema, VP ;
Wiench, JW ;
Pruski, M ;
Pecharsky, VK .
CHEMICAL COMMUNICATIONS, 2002, (07) :724-725
[3]  
BECKER WJ, 2002, CHEM COMMUN, P1602
[4]   Neutron scattering studies of pressure induced phase transitions in NH4HSO4 [J].
Bobrowicz, L ;
Natkaniec, I ;
Sarga, T ;
Bragin, SI .
HIGH PRESSURE RESEARCH, 1995, 14 (1-3) :61-65
[5]   Crystal structure and vibrational study of phase transition in the new material Cs0.86(NH4)0.14(HSO4)0.66(HSeO4)0.34 [J].
Bouattour, S ;
Mhiri, T ;
Kolsi, AW ;
Romain, F ;
Jaud, J .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2001, 62 (11) :1985-1990
[6]   Mechanochemical and solution preparation of the coordination polymers Ag[N(CH2CH2)3N]2[CH3COO]•5H2O and Zn[N(CH2CH2)3N]Cl2 [J].
Braga, D ;
Giaffreda, SL ;
Grepioni, F ;
Polito, M .
CRYSTENGCOMM, 2004, 6 :458-462
[7]   Crystal engineering, where from? Where to? [J].
Braga, D .
CHEMICAL COMMUNICATIONS, 2003, (22) :2751-2754
[8]   Reactions between or within molecular crystals [J].
Braga, D ;
Grepioni, F .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (31) :4002-4011
[9]   Hydrogen bonding interactions between ions: A powerful tool in molecular crystal engineering [J].
Braga, D ;
Maini, L ;
Polito, M ;
Grepioni, F .
SUPRAMOLECULAR ASSEMBLY VIA HYDROGEN BONDS II, 2004, 111 :1-+
[10]   Supramolecular complexation of alkali cations through mechanochemical reactions between crystalline solids [J].
Braga, D ;
Maini, L ;
Giaffreda, SL ;
Grepioni, F ;
Chierotti, MR ;
Gobetto, R .
CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (13) :3261-3269
123456