Synthesis, Crystal Structure, and Luminescence of a 1D Chain Cd(II) Polymer with 3,3′,5,5′-Benzene-1,3-biyl-tetrabenzoic Acid

被引：0
作者：
Zhang Mei-Li [1 ]
Qiao Lei [1 ]
Ma Zhen-Zhen [1 ]
Zhao Xiao-Long [1 ]
机构：
[1] Yanan Univ, Dept Chem & Chem Engn, Shaanxi Key Lab Chem React Engn, Yanan 716000, Shaanxi, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2017年 / 36卷 / 09期
关键词：
coordination polymer; synthesis; crystal structure; luminescent properties; LANTHANIDE-COORDINATION POLYMERS; METAL-ORGANIC FRAMEWORKS; MAGNETIC-PROPERTIES; MIXED-LIGANDS; COMPLEXES; DESIGN; SERIES;
D O I：
10.14102/j.cnki.0254-5861.2011-1529
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new Cd(II) coordination polymer, [Cd(H(2)btb)(bpy)](n) (1, H(4)btb = 3,3',5,5'-benzene1,3-biyl-tetrabenzoicacid, bpy = 2,2'-bipyridine), has been synthesized and characterized by elemental analysis, IR spectroscopy, thermogravimetric (TG) analyses and single-crystal X-ray diffraction techniques. Complex 1 belongs to monoclinic system, C2/c space group. In 1, two carboxylate groups of the H(4)btb ligand adopt bidentate chelating and mu(2)-eta(1):eta(1) coordination modes, respectively, bridging the Cd(II) atoms to generate a 1D polymeric ribbon. In addition, the photoluminescence property of complex 1 has also been studied.
引用
收藏
页码：1532 / 1536
页数：5
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