Synthesis, Crystal Structure, and Luminescence of a 1D Chain Cd(II) Polymer with 3,3′,5,5′-Benzene-1,3-biyl-tetrabenzoic Acid

被引：0

作者：

Zhang Mei-Li ^{[1
]}

Qiao Lei ^{[1
]}

Ma Zhen-Zhen ^{[1
]}

Zhao Xiao-Long ^{[1
]}

机构：

[1] Yanan Univ, Dept Chem & Chem Engn, Shaanxi Key Lab Chem React Engn, Yanan 716000, Shaanxi, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2017年 / 36卷 / 09期

关键词：

coordination polymer; synthesis; crystal structure; luminescent properties; LANTHANIDE-COORDINATION POLYMERS; METAL-ORGANIC FRAMEWORKS; MAGNETIC-PROPERTIES; MIXED-LIGANDS; COMPLEXES; DESIGN; SERIES;

D O I：

10.14102/j.cnki.0254-5861.2011-1529

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new Cd(II) coordination polymer, [Cd(H(2)btb)(bpy)](n) (1, H(4)btb = 3,3',5,5'-benzene1,3-biyl-tetrabenzoicacid, bpy = 2,2'-bipyridine), has been synthesized and characterized by elemental analysis, IR spectroscopy, thermogravimetric (TG) analyses and single-crystal X-ray diffraction techniques. Complex 1 belongs to monoclinic system, C2/c space group. In 1, two carboxylate groups of the H(4)btb ligand adopt bidentate chelating and mu(2)-eta(1):eta(1) coordination modes, respectively, bridging the Cd(II) atoms to generate a 1D polymeric ribbon. In addition, the photoluminescence property of complex 1 has also been studied.

引用

页码：1532 / 1536

页数：5

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