Liquid-Liquid Phase Transition in Aqueous Solutions of n-Hydrocarbons and Amphiphiles

被引:5
|
作者
Mirgorod, Yu. A. [1 ]
机构
[1] Kursk State Tech Univ, Kursk 305040, Russia
关键词
THERMODYNAMIC ANALYSIS;
D O I
10.1134/S1063785010100068
中图分类号
O59 [应用物理学];
学科分类号
摘要
Phase transitions in ensembles of water clusters in aqueous solutions of C11-C28 n-hydrocarbons and C2-C12 amphiphiles have been studied as dependent on the concentration and size of dissolved molecules. A critical size (approximately corresponding to the volume of undecane molecule) for water clusters is determined, which triggers the phase transition that leads to the formation of bistable amphiphile micelles.
引用
收藏
页码:892 / 894
页数:3
相关论文
共 50 条
  • [21] Behavior of supercooled aqueous solutions stemming from hidden liquid-liquid transition in water
    Biddle, John W.
    Holten, Vincent
    Anisimov, Mikhail A.
    JOURNAL OF CHEMICAL PHYSICS, 2014, 141 (07):
  • [22] Liquid-liquid equilibria of hydrocarbons with N-formylmorpholine
    Cincotti, A
    Murru, M
    Cao, G
    Marongiu, B
    Masia, F
    Sannia, M
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1999, 44 (03): : 480 - 483
  • [23] Liquid-liquid equilibria of hydrocarbons with N-formylmorpholine
    Dipto. Ingegneria Chim. e Materiali, Univ. degli Studi di Cagliari, Piazza d'Armi, 09123 Cagliari, Italy
    不详
    不详
    J Chem Eng Data, 3 (480-483):
  • [24] Liquid-liquid phase separation of N-isopropylpropionamide aqueous solutions above the lower critical solution temperature
    Mochizuki, Kenji
    Sumi, Tomonari
    Koga, Kenichiro
    SCIENTIFIC REPORTS, 2016, 6
  • [25] Protein phase behavior in aqueous solutions: Crystallization, liquid-liquid phase separation, gels, and aggregates
    Dumetz, Andre C.
    Chockla, Aaron M.
    Kaler, Eric W.
    Lenhoff, Abraham M.
    BIOPHYSICAL JOURNAL, 2008, 94 (02) : 570 - 583
  • [26] Probing the influence of polymer architecture on liquid-liquid phase transitions of aqueous poly(N,N-dimethylacrylamide) copolymer solutions
    Yin, XC
    Stöver, HDH
    MACROMOLECULES, 2005, 38 (06) : 2109 - 2115
  • [27] Spatial heterogeneity in liquid-liquid phase transition
    Duan, Yun-Rui
    Li, Tao
    Wu, Wei-Kang
    Li, Jie
    Zhou, Xu-Yan
    Liu, Si-Da
    Li, Hui
    CHINESE PHYSICS B, 2017, 26 (03)
  • [28] LIQUID-LIQUID PHASE TRANSITION IN SUPERCOOLED SILICON
    Vasisht, Vishwas V.
    Sastry, Srikanth
    LIQUID POLYMORPHISM, 2013, 152 : 463 - 517
  • [29] Existence of a liquid-liquid phase transition in methanol
    Hus, Matej
    Urbic, Tomaz
    PHYSICAL REVIEW E, 2014, 90 (06):
  • [30] Liquid-liquid phase transition in a system with impurity
    G. M. Rusakov
    L. D. Son
    L. I. Leont’ev
    K. Yu. Shunyaev
    Doklady Physics, 2006, 51 : 642 - 646