Reversible crystal-to-amorphous structural transformations and magnetic variations in single end-on azide-bridged MII (M = Mn, Ni) coordination polymers

被引：22
作者：
Lim, Kwang Soo [1 ]
Song, Jeong Hwa [1 ]
Kang, Dong Won [1 ]
Kang, Minjung [1 ]
Eom, Sunhwi [1 ]
Koh, Eui Kwan [2 ]
Hong, Chang Seop [1 ]
机构：
[1] Korea Univ, Dept Chem, Seoul 136713, South Korea
[2] Korea Basic Sci Inst, Nanobio Syst Res Team, Seoul 136713, South Korea
来源：
DALTON TRANSACTIONS | 2018年 / 47卷 / 03期
关键词：
HIRSHFELD SURFACE; CO-LIGANDS; COMPLEXES; FRAMEWORK; COPPER(II); NICKEL(II); CONVERSION; NETWORKS; BEHAVIOR; MN(II);
D O I：
10.1039/c7dt03886k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
M-II (M = Mn, Ni) coordination frameworks, singly linked by end-on azide ligands, were prepared by employing the long, flexible spacer ligand, p-XBP4. These two-dimensional layer structures underwent reversible crystal-to-amorphous phase transformations during the hydration-dehydration process. Moreover, the magnetic nature changes from antiferromagnetic to ferromagnetic coupling when moving from Mn to Ni.
引用
收藏
页码：845 / 851
页数：7
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