Reversible crystal-to-amorphous structural transformations and magnetic variations in single end-on azide-bridged MII (M = Mn, Ni) coordination polymers

被引：22

作者：

Lim, Kwang Soo ^{[1
]}

Song, Jeong Hwa ^{[1
]}

Kang, Dong Won ^{[1
]}

Kang, Minjung ^{[1
]}

Eom, Sunhwi ^{[1
]}

Koh, Eui Kwan ^{[2
]}

Hong, Chang Seop ^{[1
]}

机构：

[1] Korea Univ, Dept Chem, Seoul 136713, South Korea

[2] Korea Basic Sci Inst, Nanobio Syst Res Team, Seoul 136713, South Korea

来源：

DALTON TRANSACTIONS | 2018年 / 47卷 / 03期

关键词：

HIRSHFELD SURFACE; CO-LIGANDS; COMPLEXES; FRAMEWORK; COPPER(II); NICKEL(II); CONVERSION; NETWORKS; BEHAVIOR; MN(II);

D O I：

10.1039/c7dt03886k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

M-II (M = Mn, Ni) coordination frameworks, singly linked by end-on azide ligands, were prepared by employing the long, flexible spacer ligand, p-XBP4. These two-dimensional layer structures underwent reversible crystal-to-amorphous phase transformations during the hydration-dehydration process. Moreover, the magnetic nature changes from antiferromagnetic to ferromagnetic coupling when moving from Mn to Ni.

引用

页码：845 / 851

页数：7

共 2 条

[1] Reversible Crystal-to-Amorphous Structural Conversion in the Single End-On Azide-Bridged CoII Complex: Concomitant Color and Magnetic Modulations
Lim, Kwang Soo
Ryu, Dae Won
Lee, Woo Ram
Koh, Eui Kwan
Kim, Hyoung Chan
Hong, Chang Seop
CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (37) : 11541 - 11544
[2] Ferromagnetically coupled single-chain magnets exhibiting a magnetic hysteresis of 0.42 Tesla in cyano-bridged Fe2III MII (M = Ni, Fe) coordination polymers
Wang, Jin-Hua
Javed, Mohammad Khurram
Li, Jia-Xin
Zhang, Yi-Quan
Li, Zhao-Yang
Yamashita, Masahiro
DALTON TRANSACTIONS, 2023, 52 (42) : 15510 - 15517

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