Radiochemical study of gas-phase reactions of nucleogenic diethylgermyl cations with dibutyl ether and 1-butanol

被引:4
作者
Alferova, A. A. [1 ]
Kochina, T. A. [2 ]
Avrorin, V. V. [1 ]
Sinotova, E. N. [1 ]
Vrazhnov, D. V. [2 ]
机构
[1] St Petersburg State Univ, St Petersburg 198504, Russia
[2] Russian Acad Sci, Grebenshchikov Inst Chem Silicates, St Petersburg 199034, Russia
基金
俄罗斯基础研究基金会;
关键词
BuOH; Main Reaction Product; Germyl; Dibutyl Ether; Radiochemical Study;
D O I
10.1134/S1070363211070164
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Reactions of tritium-labeled free diethylgermyl cations with dibutyl ether and 1-butanol in a gas phase were studied by the radiochemical method. Mechanisms of the corresponding ion-molecular reactions were suggested, and the most probable paths of the cation (C2H5)(2)TGe+ conversion into other isomeric forms were shown.
引用
收藏
页码:1507 / 1510
页数:4
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