Synthesis, complexation and fluorescence behavior of diaza-12-crown-4 carrying two naphthyl pendants

被引：10

作者：

Kubo, K ^{[1
]}

Yamamoto, E

Sakurai, T

机构：

[1] Kyushu Univ 86, Inst Adv Mat Study, Kasuga, Fukuoka 8168580, Japan

[2] Kanagawa Univ, Fac Engn, Dept Appl Chem, Kanagawa Ku, Yokohama, Kanagawa 2210802, Japan

来源：

HETEROCYCLES | 1998年 / 48卷 / 10期

关键词：

D O I：

10.3987/COM-98-8285

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N,N'-Bis(1-naphthylmethyl)-4, 10-diaza-12-crown-4, (2) was found to display unique photophysical properties in the presence of the guest metal salts. The diazacrown (2) exhibited high Zn2+ enhancement selectivity and in the presence of this cation the host fluorescence intensities were increased by a factor of 43. The guest cation-induced fluorescence recovery of 2 was higher than N,N'-bis(1-naphthylmethyl)-4,13-diaza-18-crown-6 (1).

引用

页码：2133 / 2139

页数：7

共 27 条

[1] NATURE AND STABILITY OF SOME METALLIC COMPLEXES OF DINUCLEATING-CRYPTANDS IN SOLUTION - A POLYAZAPOLYOXA CYLINDRICAL MACROTRICYCLE AND ITS MONOCYCLIC SUBUNIT [J].

ARNAUDNEU, F ;

SANCHEZ, M ;

YAHYA, R ;

SCHWINGWEILL, MJ ;

LEHN, JM .

HELVETICA CHIMICA ACTA, 1985, 68 (02) :456-464

[2]

BRADSHAW JS, 1995, AZA CROWN MACROCYCLE

[3] Fluorescent diaza crown ether sensitive to complexation, conformation and microenvironment [J].

Collins, GE ;

Choi, LS .

CHEMICAL COMMUNICATIONS, 1997, (12) :1135-1136

[4] Selective D-glucosamine hydrochloride fluorescence signalling based on ammonium cation and diol recognition [J].

Cooper, CR ;

James, TD .

CHEMICAL COMMUNICATIONS, 1997, (15) :1419-1420

[5] THE DESIGN OF MOLECULAR HOSTS, GUESTS, AND THEIR COMPLEXES (NOBEL LECTURE) [J].

CRAM, DJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (08) :1009-1020

[6] GEOMETRICAL REQUIREMENTS FOR FLUORESCENT INTRAMOLECULAR EXCIPLEX FORMATION AND FLUORESCENCE QUENCHING [J].

DAVIDSON, RS ;

TRETHEWEY, KR .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1976, (20) :827-829

[7] Photoionic devices with receptor-functionalized fluorophores [J].

de Silva, AP ;

Gunaratne, HQN ;

Gunnlaugsson, T ;

McCoy, CP ;

Maxwell, PRS ;

Rademacher, JT ;

Rice, TE .

PURE AND APPLIED CHEMISTRY, 1996, 68 (07) :1443-1448

[8]

Fabrizzi L, 1995, CHEM SOC REV, P197

[9] N,N'-bis(1-pyrenylmethyl)-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane [J].

Kubo, K ;

Kato, N ;

Sakurai, T .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1997, 53 :132-134

[10] Synthesis and complexation behavior of N,N′-bis(1-naphthylmethyl)-1,4,10,13-tetraoxa-7,16-diazacyclo-octadecane [J].

Kubo, K ;

Ishige, R ;

Kato, N ;

Yamamoto, E ;

Sakurai, T .

HETEROCYCLES, 1997, 45 (12) :2365-2379

← 1 2 3 →