Direct proline catalyzed asymmetric α-aminooxylation of aldehydes

被引：298

作者：

Hayashi, Y ^{[1
]}

Yamaguchi, J ^{[1
]}

Hibino, K ^{[1
]}

Shoji, M ^{[1
]}

机构：

[1] Univ Tokyo, Fac Engn, Dept Ind Chem, Shinjuku Ku, Tokyo 1628601, Japan

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 45期

关键词：

organocatalyst; asymmetric reaction; catalytic reaction; proline; alpha-aminooxylation;

D O I：

10.1016/j.tetlet.2003.09.057

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The direct catalytic enantioselective alpha-aminooxylation of aldehydes has been developed using nitrosobenzene as the oxygen source and L-proline as catalyst, affording versatile alpha-aminooxylated aldehydes in high yield with excellent enantioselectivities. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：8293 / 8296

页数：4

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