1D polyoxometalate-based inorganic-organic hybrid derived from β-octamolybdate -: Synthesis and crystal structure of [CoII(2,2′-bipy)2]2[Mo8O26]

被引：7
作者：
Wang, CM
Zeng, QX
Zhang, J
Yang, GY [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China
[2] Nanjing Univ, State Key Lab Coordinat Chem, Jiangsu 210093, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2005年 / 631卷 / 05期
关键词：
polyoxometalate; inorganic-organic hybrid; beta-octamolybdate; crystal structure;
D O I：
10.1002/zaac.200400441
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A polyoxometalate-based inorganic- organic hybrid compound [Co-II(2,2 '-bPY)(2)](2)[Mo8O26] (1) was synthesized by hydrothermal methods and structurally characterized by IR spectrum, TG analysis and X-ray diffraction. The compound crystallizes in the monoclinic system, space group P2(1)/n, a = 10.0681(2), b = 16.4467(2), c = 15.7838(3) angstrom, beta = 100.046(l)-, V = 2573.52(8) angstrom(3), Z = 2. The structure of 1 is built up from beta-[Mo8O26](4-) subunits covalently linked via [Co-II(2,2 '-bpy)(2)](2+) fragments into a infinite ID {[Co-II(2,2 '-bpy)(2)](2)[MO8O26]}(proportional to)- polymer.
引用
收藏
页码：838 / 840
页数：3
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