A New Simple Model to Calculate the Heat Capacity of Pure Ionic Liquids

被引:5
作者
Azadfar, R. [1 ]
Shaabanzadeh, M. [2 ]
Hashemi-Moghaddam, H. [1 ]
Nafchi, A. Mohammadi [2 ]
机构
[1] Islamic Azad Univ, Dept Chem & Chem Engn, Damghan Branch, Damghan, Iran
[2] Univ Sains Malaysia, Sch Ind Technol, George Town 11800, Malaysia
来源
PHYSICAL CHEMISTRY RESEARCH | 2020年 / 8卷 / 01期
关键词
Heat capacity; Ionic liquid; Correlation; NISI; CO2; SOLUBILITY; H2S;
D O I
10.22036/pcr.2019.204016.1681
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In recent years, there is a great attention toward the ionic liquids due to their huge potential for separation and reaction technology. Also, the heat capacity of ionic liquids is a substantial parameter for conclusive process designs and engineering calculations. A database for the heat capacity of ionic liquids created by compiling experimental data in the literature covering a period from 1971 to 2016 is reported. In this work, a temperature-dependent equation to the heat capacity for 141 pure ionic liquids is proposed. A database containing 6961 experimental data was used to develop this model. Finally, a 7-parameter simple equation with the capability for predicting the heat capacity of ionic liquids is presented. The accuracy of the new model has been compared to the most precise models in the literature and the comparison indicates that the proposed method provides more accurate results than other models considered in this work. The average absolute percentage deviation from the new model is only 3.83%.
引用
收藏
页码:139 / 154
页数:16
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