Palladium-catalyzed inter- and intramolecular hydroamination of styrenes coupled with alcohol oxidation using N-fluorobenzenesulfonimide as the oxidant

被引：35

作者：

Xu, Tao ^{[1
]}

Qiu, Shuifa ^{[1
]}

Liu, Guosheng ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2011年 / 696卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Palladium; Alcohol oxidation; Hydroamination; Styrene; ANTI-MARKOVNIKOV HYDROAMINATION; NITROGEN-DONOR LIGANDS; UNACTIVATED ALKENES; TRANSFER HYDROGENATION; CIS-AMINOPALLADATION; COMPLEXES; ALLENES; ALKYNES; VINYLARENES; OLEFINS;

D O I：

10.1016/j.jorganchem.2010.07.015

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Palladium-catalyzed inter- and intramolecular hydroaminations of styrenes that are coupled to alcohol oxidation under oxidative condition are reported. The fluorination reagent NFSI is used as the nitrogen source as well as the oxidant. Bidental nitrogen ligand bathocuproine plays a crucial role in this transformation. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：46 / 49

页数：4

共 54 条

[1] Use of group 4 bis(sulfonamido) complexes in the intramolecular hydroamination of alkynes and allenes [J].