Pressure-broadening coefficients and line strengths of H2O near 1.39 μm:: application to the in situ sensing of the middle atmosphere with balloonborne diode lasers

被引:34
作者
Durry, G
Zeninari, V
Parvitte, B
Le barbu, T
Lefevre, F
Ovarlez, J
Gamache, RR
机构
[1] CNRS, UMR 6089, UFR Sci Exactes & Nat, Grp Spectrometrie Mol & Atmospher, F-51687 Reims, France
[2] CNRS Reduit Verrieres, Serv Aeron, F-91371 Verrieres Le Buisson, France
[3] Ecole Polytech, UMR 8539, Meteorol Dynam Lab, F-91128 Palaiseau, France
[4] Univ Massachusetts Lowell, Dept Environm Earth & Atmospher Sci, Lowell, MA 01854 USA
基金
美国国家科学基金会;
关键词
diode laser; near-infrared spectrometer; ab initio calculations; water vapor; atmospheric applications;
D O I
10.1016/j.jqsrt.2004.09.033
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Since 1998, we have developed two balloonborne diode laser spectrometers, SDLA and micro-SDLA, to yield in situ concentration data of H2O in the middle atmosphere by absorption spectroscopy in the 1.39 mu m spectral range. In this paper, we revisit the molecular parameters, line intensities and pressure-broadening coefficients, for several lines of the nu(1) + nu(3) and 2 nu(1) bands, which are useful for the monitoring of atmospheric H2O. The new values are thoroughly compared to existing molecular database and previous determinations. Calculations are performed to yield the pressure-effect coefficients: the theoretical model is described and the ab initio predictions are compared to laboratory measurements achieved with a laser diode spectrometer. The improvement in the H2O monitoring obtained with the new set of molecular data is evaluated directly from vertical H2O concentration profiles. (c) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:387 / 403
页数:17
相关论文
共 44 条
[1]   GENERAL IMPACT THEORY OF PRESSURE BROADENING [J].
BARANGER, M .
PHYSICAL REVIEW, 1958, 112 (03) :855-865
[2]  
BENREUVEN A, 1975, ADV CHEM PHYS, V20, P235
[3]  
Bogaard MP, 1975, MTP INT REV SCI PH 2, V2
[4]   HIGHER RO-VIBRATIONAL LEVELS OF H2O DEDUCED FROM HIGH-RESOLUTION OXYGEN-HYDROGEN FLAME SPECTRA BETWEEN 6200 AND 9100 CM-1 [J].
CAMYPEYRET, C ;
FLAUD, JM ;
MAILLARD, JP ;
GUELACHVILI, G .
MOLECULAR PHYSICS, 1977, 33 (06) :1641-1650
[5]   ADJUSTABLE-TEMPERATURE AND MULTIPLE-PATH OPTICAL-CELL FOR OZONE SPECTROSCOPY [J].
COURTOIS, D ;
DELAHAIGUE, A ;
THIEBEAUX, C ;
LECORRE, H ;
MOUANDA, JC .
JOURNAL OF PHYSICS E-SCIENTIFIC INSTRUMENTS, 1988, 21 (09) :863-865
[6]   CALCULATED TABULATIONS OF H2O LINE BROADENING BY H2O,N2,O2, AND CO2 AT HIGH-TEMPERATURE [J].
DELAYE, C ;
HARTMANN, JM ;
TAINE, J .
APPLIED OPTICS, 1989, 28 (23) :5080-5087
[7]   Atmospheric CH4 and H2O monitoring with near-infrared InGaAs laser diodes by the SDLA, a balloonborne spectrometer for tropospheric and stratospheric in situ measurements [J].
Durry, G ;
Megie, G .
APPLIED OPTICS, 1999, 38 (36) :7342-7354
[8]   In situ measurements of H2O from a stratospheric balloon by diode laser direct-differential absorption spectroscopy at 1.39 μm [J].
Durry, G ;
Megie, G .
APPLIED OPTICS, 2000, 39 (30) :5601-5608
[9]  
Durry G, 2001, J ATMOS OCEAN TECH, V18, P1485, DOI 10.1175/1520-0426(2001)018<1485:ANIDLS>2.0.CO
[10]  
2